A remarkable phosphorescent sensor for acid–base vapours based on an AIPE-active Ir(iii) complex

2019 ◽  
Vol 48 (6) ◽  
pp. 1955-1959 ◽  
Author(s):  
Dan Li ◽  
Guangfu Li ◽  
Weilong Che ◽  
Dongxia Zhu ◽  
Zhongmin Su

A novel AIPE-active neutral mononuclear Schiff base ligand Ir(iii) complex has been synthesized for rapid and reversible phosphorescent sensing of acid–base vapours.

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Gulsah Gumrukcu ◽  
Serkis Garikyan ◽  
Gulnur Keser Karaoglan ◽  
Dolunay Sakar

A new Schiff base with D-π-D type, (1E,2E)-3-[4-(dimethylamino)phenyl]prop-2-en-1-ylidene)phenylamine, has been successfully synthesized using the reaction of (2E)-3-[4-(dimethylamino)phenyl]acrylaldehyde with aniline. The Schiff base ligand has been characterized by FTIR, UV-visible, and1H NMR as well as TG/DTA, SEM, BET, and elemental analyses and mass spectra. Surface properties and acid-base constants of Schiff base ligand were determined by IGC measurements.


2021 ◽  
Author(s):  
Cyril Rajnák ◽  
Romana Mičová ◽  
Ján Moncoľ ◽  
Ľubor Dlháň ◽  
Christoph Krüger ◽  
...  

A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).


2021 ◽  
Vol 157 ◽  
pp. 106329
Author(s):  
Tanlong Xue ◽  
Yang Li ◽  
Xiangchen Zhao ◽  
Jun Nie ◽  
Xiaoqun Zhu

Biochimie ◽  
2021 ◽  
Vol 186 ◽  
pp. 43-50
Author(s):  
María R. Rodríguez ◽  
Martín J. Lavecchia ◽  
Beatriz S. Parajón-Costa ◽  
Ana C. González-Baró ◽  
María R. González-Baró ◽  
...  

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