Synthesis of nickel and palladium complexes with diarylamido-based unsymmetrical pincer ligands and application for norbornene polymerization

2019 ◽  
Vol 48 (2) ◽  
pp. 609-617 ◽  
Author(s):  
Hui Liu ◽  
Haibin Yuan ◽  
Xiaochao Shi

Nickel and palladium complexes chelating diarylamido-based unsymmetrical [PNNox] pincer ligands have been synthesized and used as catalysts for norbornene polymerization with activities up to 40.3 × 105 g of PNB (mol of Pd)−1 h−1 upon the activation of methylaluminoxane (MAO).

Author(s):  
Javier A. Cabeza ◽  
Pablo García-Álvarez ◽  
Carlos J. Laglera ◽  
Enrique Pérez-Carreño

Author(s):  
Enrique Gutiérrez ◽  
Sarah A. Hudson ◽  
Angeles Monge ◽  
M. Carmen Nicasio ◽  
Margarita Paneque ◽  
...  

2009 ◽  
Vol 28 (4) ◽  
pp. 1180-1192 ◽  
Author(s):  
Jitte Flapper ◽  
Huub Kooijman ◽  
Martin Lutz ◽  
Anthony L. Spek ◽  
Piet W. N. M. van Leeuwen ◽  
...  

2016 ◽  
Vol 70 (8) ◽  
Author(s):  
Shane C Van Wyk ◽  
Martin O. Onani ◽  
Ebbe Nordlander

AbstractSouth Africa is a mineral-rich country and one area in which minerals can be very important is catalysis. Over an extended period of time, homogeneous catalysis has grown to become very useful, particularly in the chemical and pharmaceutical industries. The organometallic compounds required in the catalysis industry have advanced from metallocenes to an alternative in the form of


2009 ◽  
Vol 28 (20) ◽  
pp. 5934-5940 ◽  
Author(s):  
Yong Kong ◽  
Hongping Ren ◽  
Shansheng Xu ◽  
Haibin Song ◽  
Binyuan Liu ◽  
...  

2018 ◽  
Vol 9 (10) ◽  
pp. 1234-1248 ◽  
Author(s):  
Robert Mundil ◽  
Anatolij Sokolohorskyj ◽  
Jan Hošek ◽  
Josef Cvačka ◽  
Ivana Císařová ◽  
...  

Living/controlled olefin polymerization is displayed by novel nickel and palladium diimine catalysts with fluorinated tails.


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