Unveiling reactive metal sites in a Pd pincer MOF: insights into Lewis acid and pore selective catalysis

2019 ◽  
Vol 48 (26) ◽  
pp. 9588-9595 ◽  
Author(s):  
Benjamin R. Reiner ◽  
Abebu A. Kassie ◽  
Casey R. Wade
Keyword(s):  
Lewis Acid ◽  
Ligand Exchange ◽  
Acid Catalyst ◽  
Reactive Metal ◽  
Highly Active ◽  
Lewis Acid Catalyst ◽  
Selective Catalysis

NOBF4 enables efficient oxidative ligand exchange in a Pd pincer MOF, generating a highly active and recyclable Lewis acid catalyst.

scholarly journals Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis

2019 ◽  
Vol 15 ◽  
pp. 1304-1312 ◽  
Author(s):  
Qichao Zhang ◽  
Jian Lv ◽  
Sanzhong Luo
Keyword(s):  
Lewis Acid ◽  
Acid Catalyst ◽  
Alder Reaction ◽  
Ion Pair ◽  
Diels Alder ◽  
Highly Active ◽  
Diels Alder Reaction ◽  
New Type ◽  
Lewis Acid Catalyst ◽  
Trityl Cation

The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantioselective Diels–Alder reaction of anthracene.

Highly active, water-compatible and easily separable magnetic mesoporous Lewis acid catalyst for the Mukaiyama–Aldol reaction in water

2014 ◽  
Vol 16 (8) ◽  
pp. 3768-3777 ◽  
Author(s):  
Fang Zhang ◽  
Xiaotao Wu ◽  
Chao Liang ◽  
Xiaoyan Li ◽  
Zhen Wang ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Lewis Acid ◽  
Aldol Reaction ◽  
Acid Catalyst ◽  
Mukaiyama Aldol Reaction ◽  
Highly Active ◽  
Mukaiyama Aldol ◽  
Lewis Acid Catalyst ◽  
Reaction In Water ◽  
Magnetic Mesoporous Silica

A multifunctional magnetic mesoporous silica supported Yb(OTf)3 composite was demonstrated to be an efficient and easily recyclable catalyst for the Mukaiyama–Aldol reaction in water.

An extremely stable and highly active periodic mesoporous Lewis acid catalyst in water-medium Mukaiyama-aldol reaction

2013 ◽  
Vol 15 (10) ◽  
pp. 2865 ◽  
Author(s):  
Fang Zhang ◽  
Chao Liang ◽  
Mingzheng Chen ◽  
Haibing Guo ◽  
Huangyong Jiang ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Aldol Reaction ◽  
Acid Catalyst ◽  
Water Medium ◽  
Mukaiyama Aldol Reaction ◽  
Highly Active ◽  
Mukaiyama Aldol ◽  
Lewis Acid Catalyst

Fe4(SiW12O40)3-catalyzed glycerol acetylation: Synthesis of bioadditives by using highly active Lewis acid catalyst

2016 ◽  
Vol 422 ◽  
pp. 69-83 ◽  
Author(s):  
Márcio José Da Silva ◽  
Natalia Aparecida Liberto ◽  
Lorena Cristina De Andrade Leles ◽  
Ulisses Alves Pereira
Keyword(s):  
Lewis Acid ◽  
Acid Catalyst ◽  
Highly Active ◽  
Lewis Acid Catalyst
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