scholarly journals Palladium alkyl complexes with a formazanate ligand: synthesis, structure and reactivity

2018 ◽  
Vol 47 (41) ◽  
pp. 14445-14451 ◽  
Author(s):  
Francesca Milocco ◽  
Folkert de Vries ◽  
Anna Dall'Anese ◽  
Vera Rosar ◽  
Ennio Zangrando ◽  
...  
Keyword(s):  
Redox Reactions ◽  
Palladium Complexes ◽  
Alkyl Complexes ◽  
Ligand Synthesis

The synthesis of formazanate palladium complexes is reported. Ligand-based redox-reactions and insertions of unsaturated substrates into the Pd–CH3 bond are studied.

Synthesis and redox reactions of bis(verdazyl)palladium complexes

2017 ◽  
Vol 46 (37) ◽  
pp. 12636-12644 ◽  
Author(s):  
Corey A. Sanz ◽  
Zach R. McKay ◽  
Shaun W. C. MacLean ◽  
Brian O. Patrick ◽  
Robin G. Hicks
Keyword(s):  
Redox Reactions ◽  
Palladium Complexes ◽  
Redox Transformations

Bis(verdazyl)palladium complexes undergo a range of redox transformations, many of which involve ligand (hemi)lability.

scholarly journals Isocyanide insertion across the Pd–C bond of allenyl and propargyl palladium complexes bearing phosphoquinoline as a spectator ligand. Synthesis of a palladium complex bearing a coordinated cyclobutenyl fragment

2017 ◽  
Vol 46 (16) ◽  
pp. 5210-5217 ◽  
Author(s):  
Thomas Scattolin ◽  
Fabiano Visentin ◽  
Claudio Santo ◽  
Valerio Bertolasi ◽  
Luciano Canovese
Keyword(s):  
Palladium Complex ◽  
Palladium Complexes ◽  
Ligand Synthesis

A palladium complex bearing a cyclobutenyl group directly coordinated to metal has been obtained as a result of the insertion of an isocyanide across the Pd–C bond.

Rare-earth metal alkyl complexes bearing an alkoxy N-heterocyclic carbene ligand: synthesis, characterization, catalysis for isoprene polymerization

2015 ◽  
Vol 39 (10) ◽  
pp. 7682-7687 ◽  
Author(s):  
Shiyu Long ◽  
Baoli Wang ◽  
Hongyan Xie ◽  
Changguang Yao ◽  
Chunji Wu ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Alkyl Complexes ◽  
Ligand Synthesis ◽  
Isoprene Polymerization

The new rare-earth metal alkyl complexes bearing alkoxy NHC ligands were prepared, which showed moderate cis-1,4 selectivity for isoprene polymerization.

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