A ZnO/ZnFe2O4 uniform core–shell heterojunction with a tubular structure modified by NiOOH for efficient photoelectrochemical water splitting

2018 ◽  
Vol 47 (35) ◽  
pp. 12181-12187 ◽  
Author(s):  
Yayao Lan ◽  
Zhifeng Liu ◽  
Zhengang Guo ◽  
Xifei Li ◽  
Lei Zhao ◽  
...  

It is known that heterojunction photoelectrodes can improve light absorption and accelerate the separation of photogenerated carriers in the field of photoelectrochemical (PEC) water splitting.

Author(s):  
Yubin Chen ◽  
Wenyu Zhen ◽  
Sebastián Murcia-López ◽  
Fei Lv ◽  
Joan R. Morante ◽  
...  

Photoelectrochemical (PEC) water splitting is a very attractive approach to produce clean hydrogen using abundant natural resources such as solar energy and (sea)water. As its primary step, light absorption controls...


Nanoscale ◽  
2015 ◽  
Vol 7 (22) ◽  
pp. 10094-10100 ◽  
Author(s):  
Meng Wang ◽  
Myeongwhun Pyeon ◽  
Yakup Gönüllü ◽  
Ali Kaouk ◽  
Shaohua Shen ◽  
...  

Fe2O3/TiO2 nanorod arrays with core–shell structure were prepared via a facile hydrothermal and PECVD approach, which show significantly enhanced PEC water splitting ability and stability.


2019 ◽  
Author(s):  
Jiajia Tao ◽  
Hong-Ping Ma ◽  
Kaiping Yuan ◽  
Yang Gu ◽  
Jianwei Lian ◽  
...  

<div>As a promising oxygen evolution reaction semiconductor, TiO2 has been extensively investigated for solar photoelectrochemical water splitting. Here, a highly efficient and stable strategy for rationally preparing GaON cocatalysts on TiO2 by atomic layer deposition is demonstrated, which we show significantly enhances the</div><div>photoelectrochemical performance compared to TiO2-based photoanodes. For TiO2@20 nm-GaON core-shell nanowires a photocurrent density up to 1.10 mA cm-2 (1.23 V vs RHE) under AM 1.5 G irradiation (100 mW cm-2) has been achieved, which is 14 times higher than that of TiO2 NWs. Furthermore, the oxygen vacancy formation on GaON as well as the band gap matching with TiO2 not only provides more active sites for water oxidation but also enhances light absorption to promote interfacial charge separation and migration. Density functional theory studies of model systems of GaON-modified TiO2 confirm the band gap reduction, high reducibility and ability to activate water. The highly efficient and stable systems of TiO2@GaON core-shell nanowires provide a deeper understanding and universal strategy for enhancing photoelectrochemical performance of photoanodes now available. </div>


Author(s):  
Xin Zou ◽  
Xueyang Han ◽  
Chengxiong Wang ◽  
Yunkun Zhao ◽  
Chun Du ◽  
...  

Ta3N5 is regarded as a promising candidate material with adequate visible light absorption and band structure for photoelectrochemical water splitting. However, the performance of Ta3N5 is severely limited by the...


2019 ◽  
Vol 7 (14) ◽  
pp. 8061-8072 ◽  
Author(s):  
Erhuan Zhang ◽  
Jia Liu ◽  
Muwei Ji ◽  
Hongzhi Wang ◽  
Xiaodong Wan ◽  
...  

Construction of hollow anisotropic semiconductor nanostructures that possess excellent crystallinity, flexibly tunable structure/morphology and aqueous dispersity is of special interest for photoelectrochemical (PEC) water splitting


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