Computational mechanistic elucidation of the rare earth metal-mediated cycloamidination of aminoalkenes with nitriles

2018 ◽  
Vol 47 (35) ◽  
pp. 12264-12272 ◽  
Author(s):  
Sven Tobisch
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Solid Ground ◽  
Mechanistic Probe ◽  
Mechanistic View ◽  
The Rare Earth

An in-depth computational mechanistic probe of the rare earth metal-mediated cycloamidination of aminoalkenes with nitriles allowed the substitution of mechanistic hypothesis advanced previously by a computationally verified mechanistic view, thus providing solid ground for further rational catalyst improvement.

ChemInform Abstract: Eu2(CN2)3and KEu[Si(CN2)4]: Missing Members of the Rare Earth Metal Carbodiimide and Tetracyanamidosilicate Series.

ChemInform ◽  
2016 ◽  
Vol 47 (45) ◽  
Author(s):  
Danuta Dutczak ◽  
Markus Stroebele ◽  
David Enseling ◽  
Thomas Juestel ◽  
H.-Juergen Meyer
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
The Rare Earth

On the structures of the rare-earth metal germanides from the series REAl1−xGe3(RE = Nd, Sm, Gd, Tb, Dy, Ho; 0.6 < x < 0.9). A tale of vacancies at the Al sites and the concomitant structural modulations

2017 ◽  
Vol 46 (28) ◽  
pp. 9253-9265 ◽  
Author(s):  
Jiliang Zhang ◽  
Yanyan Liu ◽  
Chan Hung Shek ◽  
Yingmin Wang ◽  
Svilen Bobev
Keyword(s):  
Rare Earth ◽  
General Formula ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Average Structure ◽  
The Rare Earth

This paper discusses the germanides with the general formula REAl1−xGe3(RE = Nd, Sm, Gd–Ho), whose average structure is a defect-variant of the orthorhombic SmNiGe3.

Eu2(CN2)3and KEu[Si(CN2)4]: Missing Members of the Rare Earth Metal Carbodiimide and Tetracyanamidosilicate Series

2016 ◽  
Vol 2016 (25) ◽  
pp. 4011-4016 ◽  
Author(s):  
Danuta Dutczak ◽  
Markus Ströbele ◽  
David Enseling ◽  
Thomas Jüstel ◽  
H.-Jürgen Meyer
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
The Rare Earth
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