A water-stable lanthanide coordination polymer as a multiresponsive luminescent sensor for Fe3+, Cr(vi) and 4-nitrophenol

2018 ◽  
Vol 47 (38) ◽  
pp. 13543-13549 ◽  
Author(s):  
Yan Liu ◽  
Jingjing Ma ◽  
Cong Xu ◽  
Yang Yang ◽  
Minfang Xia ◽  
...  

Constructing water stable lanthanide coordination polymers (Ln-CPs) is of great importance for practical applications in biological and environmental areas and necessary for systematic research on the relationship between the properties of Ln-CPs and structures of linker ligands.

The Analyst ◽  
2016 ◽  
Vol 141 (8) ◽  
pp. 2347-2350 ◽  
Author(s):  
Yan-Yun Li ◽  
Xiao-Qin Jiang ◽  
Min Zhang ◽  
Guoyue Shi

A convenient one-step approach has been developed to make thermo-sensitive lanthanide coordination polymer nanoparticles (LCPNs) doped with thioflavin T.


2017 ◽  
Vol 9 (6) ◽  
pp. 1004-1010 ◽  
Author(s):  
Lili Chen ◽  
Penghui Huang ◽  
Hongliang Tan ◽  
Li Wang

Lanthanide coordination polymers (LCPs) have attracted great interest because of their special photophysical properties, diverse compositions and architecture.


2018 ◽  
Vol 10 (50) ◽  
pp. 44109-44115 ◽  
Author(s):  
Liang Li ◽  
Jiahui Cheng ◽  
Zhipeng Liu ◽  
Lin Song ◽  
Yujian You ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (103) ◽  
pp. 100743-100747 ◽  
Author(s):  
Baoxia Liu ◽  
Yankai Huang ◽  
Qi Shen ◽  
Xu Zhu ◽  
Yuanqiang Hao ◽  
...  

Metal–organic coordination polymers (MOCPs) have emerged as a new family of functional nanomaterials.


2015 ◽  
Vol 44 (8) ◽  
pp. 3764-3772 ◽  
Author(s):  
Hung-Kai Feng ◽  
Po-Jung Huang ◽  
Hui-Lien Tsai

The one-dimensional Dy coordination polymer displays a single-ion magnetic behaviour with a narrow distribution of relaxation under a dc field.


2019 ◽  
Vol 11 (10) ◽  
pp. 1405-1409 ◽  
Author(s):  
Haoshuang Shen ◽  
Baoxia Liu ◽  
Daosheng Liu ◽  
Xu Zhu ◽  
Xiuhua Wei ◽  
...  

GMP ligand based LCP sensor for Cit with high sensitivity and selectivity was constructed.


Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1101
Author(s):  
Anirban Karmakar ◽  
Anup Paul ◽  
Elia Pantanetti Sabatini ◽  
M. Fátima C. Guedes da Silva ◽  
Armando J. L. Pombeiro

The new coordination polymers (CPs) [Zn(μ-1κO1:1κO2-L)(H2O)2]n·n(H2O) (1) and [Cd(μ4-1κO1O2:2κN:3,4κO3-L)(H2O)]n·n(H2O) (2) are reported, being prepared by the solvothermal reactions of 5-{(pyren-4-ylmethyl)amino}isophthalic acid (H2L) with Zn(NO3)2.6H2O or Cd(NO3)2.4H2O, respectively. They were synthesized in a basic ethanolic medium or a DMF:H2O mixture, respectively. These compounds were characterized by single-crystal X-ray diffraction, FTIR spectroscopy, thermogravimetric and elemental analysis. The single-crystal X-ray diffraction analysis revealed that compound 1 is a one dimensional linear coordination polymer, whereas 2 presents a two dimensional network. In both compounds, the coordinating ligand (L2−) is twisted due to the rotation of the pyrene ring around the CH2-NH bond. In compound 1, the Zn(II) metal ion has a tetrahedral geometry, whereas, in 2, the dinuclear [Cd2(COO)2] moiety acts as a secondary building unit and the Cd(II) ion possesses a distorted octahedral geometry. Recently, several CPs have been explored for the cyanosilylation reaction under conventional conditions, but microwave-assisted cyanosilylation of aldehydes catalyzed by CPs has not yet been well studied. Thus, we have tested the solvent-free microwave-assisted cyanosilylation reactions of different aldehydes, with trimethylsilyl cyanide, using our synthesized compounds, which behave as highly active heterogeneous catalysts. The coordination polymer 1 is more effective than 2, conceivably due to the higher Lewis acidity of the Zn(II) than the Cd(II) center and to a higher accessibility of the metal centers in the former framework. We have also checked the heterogeneity and recyclability of these coordination polymers, showing that they remain active at least after four recyclings.


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