Iron catalyzed oxidation of benzylic alcohols to benzoic acids

2018 ◽  
Vol 47 (18) ◽  
pp. 6412-6420 ◽  
Author(s):  
B. Stanje ◽  
P. Traar ◽  
J. A. Schachner ◽  
F. Belaj ◽  
N. C. Mösch-Zanetti
Keyword(s):  
Benzoic Acid ◽  
Benzoic Acids ◽  
One Pot ◽  
Benzyl Alcohols ◽  
Benzylic Alcohols ◽  
Catalyzed Oxidation

Direct, one-pot oxidation of benzyl alcohols to benzoic acid with H2O2 catalyzed by Fe(iii) complexes.

Palladium-Catalyzed Decarboxylation of Benzyl Fluorobenzoates

Synlett ◽  
2017 ◽  
Vol 28 (19) ◽  
pp. 2573-2576 ◽  
Author(s):  
Ryoichi Kuwano ◽  
Yusuke Makida ◽  
Yasutaka Matsumoto
Keyword(s):  
Benzoic Acid ◽  
Catalytic Reaction ◽  
Functional Group ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Benzoic Acids ◽  
Benzyl Alcohols ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed

The decarboxylation of benzyl fluorobenzoates has been developed by using the palladium catalyst prepared in situ from Pd(η3-allyl)Cp and bulky monophosphine ligand XPhos. The catalytic reaction afforded a range of fluorinated diarylmethanes in good yields with broad functional-group compatibility. The substrates were readily synthesized by condensation of the corresponding benzoic acid with benzyl alcohol. Therefore, the transformation is formally regarded as a cross-coupling reaction between fluorine-containing benzoic acids and benzyl alcohols.

One-Pot Synthesis and Conformational Analysis of 6-Membered Cyclic Iodonium Salts

2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim
Keyword(s):  
Conformational Analysis ◽  
Bronsted Acids ◽  
One Pot ◽  
Benzyl Alcohols ◽  
Iodonium Salts ◽  
Efficient Approach ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>

scholarly journals Hydrogenation of benzoic acid derivatives over Pt/TiO2 under mild conditions

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Miao Guo ◽  
Xiangtao Kong ◽  
Chunzhi Li ◽  
Qihua Yang
Keyword(s):  
Electron Transfer ◽  
Benzoic Acid ◽  
High Efficiency ◽  
Carboxyl Groups ◽  
Carboxyl Group ◽  
Benzoic Acids ◽  
Catalyst Poisoning ◽  
Benzoic Acid Derivatives ◽  
Mild Conditions ◽  
Transfer Direction

AbstractHydrogenation of benzoic acid (BA) to cyclohexanecarboxylic acid (CCA) has important industrial and academic significance, however, the electron deficient aromatic ring and catalyst poisoning by carboxyl groups make BA hydrogenation a challenging transformation. Herein, we report that Pt/TiO2 is very effective for BA hydrogenation with, to our knowledge, a record TOF of 4490 h−1 at 80 °C and 50 bar H2, one order higher than previously reported results. Pt/TiO2 catalysts with electron-deficient and electron-enriched Pt sites are obtained by modifying the electron transfer direction between Pt and TiO2. Electron-deficient Pt sites interact with BA more strongly than electron-rich Pt sites, helping the dissociated H of the carboxyl group to participate in BA hydrogenation, thus enhancing its activity. The wide substrate scope, including bi- and tri-benzoic acids, further demonstrates the high efficiency of Pt/TiO2 for hydrogenation of BA derivatives.

N-Functionalized Amino Acids Promoted Aerobic Copper-Catalyzed Oxidation of Benzylic Alcohols in Water

Synlett ◽  
2015 ◽  
Vol 26 (06) ◽  
pp. 779-784 ◽  
Author(s):  
Chengrong Ding ◽  
Shang Shan ◽  
Guofu Zhang ◽  
Jie Lei ◽  
Xingwang Han ◽  
...  
Keyword(s):  
Amino Acids ◽  
Benzylic Alcohols ◽  
Functionalized Amino Acids ◽  
Catalyzed Oxidation

Rapid Mo(CO)6 Catalyzed One-Pot Deoxygenation of Heterocyclic Halo-Benzyl Alcohols with Lawesson′s Reagent.

ChemInform ◽  
2005 ◽  
Vol 36 (26) ◽  
Author(s):  
Xiongyu Wu ◽  
A. K. Mahalingam ◽  
Mathias Alterman
Keyword(s):  
One Pot ◽  
Benzyl Alcohols

Iron-catalyzed one-pot synthesis of benzimidazoles from 2-nitroanilines and benzylic alcohols

2013 ◽  
Vol 54 (50) ◽  
pp. 6934-6936 ◽  
Author(s):  
Gang Li ◽  
Jin Wang ◽  
Baokun Yuan ◽  
Dongfeng Zhang ◽  
Ziyun Lin ◽  
...  
Keyword(s):  
One Pot ◽  
Benzylic Alcohols ◽  
One Pot Synthesis

One-pot synthesis of 2-(1-acyloxypentyl) benzoic acids

2008 ◽  
Vol 19 (8) ◽  
pp. 915-917 ◽  
Author(s):  
Zhen Li Min ◽  
Yi Hua Zhang ◽  
Yi Sheng Lai ◽  
Si Xun Peng
Keyword(s):  
Benzoic Acids ◽  
One Pot ◽  
One Pot Synthesis

Metal-free one-pot α -benzoxylation of benzylic alcohols with acids or aldehydes

2018 ◽  
Vol 59 (4) ◽  
pp. 368-371 ◽  
Author(s):  
Yefu Zhu ◽  
Yong Zheng ◽  
Weibin Song ◽  
Bole Wei ◽  
Lijiang Xuan
Keyword(s):  
One Pot ◽  
Benzylic Alcohols ◽  
Metal Free
Sign in / Sign up

Export Citation Format

Share Document