A multifunctional MOF as a recyclable catalyst for the fixation of CO2 with aziridines or epoxides and as a luminescent probe of Cr(vi)

2018 ◽  
Vol 47 (13) ◽  
pp. 4545-4553 ◽  
Author(s):  
Chun-Shuai Cao ◽  
Ying Shi ◽  
Hang Xu ◽  
Bin Zhao
Keyword(s):  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Luminescent Probe ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Organic Framework

A multifunctional metal-organic framework (1) can serve as an efficient and recyclable catalysts for the conversion of CO2 with aziridines or epoxides. Furthermore, the material can also act as a recyclable luminescent probe for Cr(vi) species among twenty anions.

scholarly journals Recyclable Catalysts for Alkyne Functionalization

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3525
Author(s):  
Leslie Trigoura ◽  
Yalan Xing ◽  
Bhanu P. S. Chauhan
Keyword(s):  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Nanoparticle ◽  
Homogeneous Catalyst ◽  
Catalyst Recycling ◽  
Catalytic Systems ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Porous Organic Framework ◽  
Organic Framework

In this review, we present an assessment of recent advances in alkyne functionalization reactions, classified according to different classes of recyclable catalysts. In this work, we have incorporated and reviewed the activity and selectivity of recyclable catalytic systems such as polysiloxane-encapsulated novel metal nanoparticle-based catalysts, silica–copper-supported nanocatalysts, graphitic carbon-supported nanocatalysts, metal organic framework (MOF) catalysts, porous organic framework (POP) catalysts, bio-material-supported catalysts, and metal/solvent free recyclable catalysts. In addition, several alkyne functionalization reactions have been elucidated to demonstrate the success and efficiency of recyclable catalysts. In addition, this review also provides the fundamental knowledge required for utilization of green catalysts, which can combine the advantageous features of both homogeneous (catalyst modulation) and heterogeneous (catalyst recycling) catalysis.

scholarly journals A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP

2016 ◽  
Vol 7 (47) ◽  
pp. 7199-7203 ◽  
Author(s):  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Atom Transfer ◽  
Arget Atrp ◽  
Metal Organic ◽  
Organic Framework

A Cu(ii) MOF can serve as an comprehensive catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) in the synthesis of benzyl methacrylate, styrene, isoprene and 4-vinylpyridine.

Metal organic framework derived magnetic porous carbon composite supported gold and palladium nanoparticles as highly efficient and recyclable catalysts for reduction of 4-nitrophenol and hydrodechlorination of 4-chlorophenol

2014 ◽  
Vol 2 (44) ◽  
pp. 18775-18785 ◽  
Author(s):  
Zhengping Dong ◽  
Xuanduong Le ◽  
Yansheng Liu ◽  
Chunxu Dong ◽  
Jiantai Ma
Keyword(s):  
Porous Carbon ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Catalyst Support ◽  
Carbon Composite ◽  
Highly Efficient ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Supported Gold ◽  
Organic Framework

A magnetic porous carbon composite which has been synthesized from MOF is used as a catalyst support to fabricate Au and Pd NP based nanocatalysts.

A sensitive metal–organic framework nanosensor with cation-introduced chirality for enantioselective recognition and determination of quinine and quinidine in human urine

2020 ◽  
Vol 8 (41) ◽  
pp. 14579-14586
Author(s):  
Tian-Yu Liu ◽  
Xiang-Long Qu ◽  
Bing Yan
Keyword(s):  
Human Urine ◽  
Metal Organic Framework ◽  
Luminescent Probe ◽  
Enantioselective Recognition ◽  
Metal Organic ◽  
Chiral Centers ◽  
Organic Framework

Additional chiral centers have been introduced into Cd-MOF to prepare a novel luminescent probe (1-C-Eu), which demonstrates promise in the enantioselective recognition and detection of quinine and quinidine in human urine.

A novel trinuclear Cd(ii) cluster-based metal–organic framework: synthesis, structure and luminescence properties

RSC Advances ◽  
2015 ◽  
Vol 5 (124) ◽  
pp. 102525-102529 ◽  
Author(s):  
Jia Wang ◽  
Shuo Yao ◽  
Guanghua Li ◽  
Qisheng Huo ◽  
Lirong Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Luminescence Properties ◽  
Luminescent Probe ◽  
Metal Organic ◽  
Organic Framework

A novel luminescent Cd-MOF based on trinuclear Cd cluster and H2PZC ligand has been constructed, it may be used as a potential luminescent probe for the detection of acetone, Na+ and Fe2+.

A direct strategy to synthesize hybrid benzothiazole–carbamate moieties via O-acylation of phenols under metal–organic framework catalysis

2017 ◽  
Vol 2 (5) ◽  
pp. 669-678 ◽  
Author(s):  
Chung K. Nguyen ◽  
Nguyen B. Nguyen ◽  
Oanh N. Chu ◽  
Ha V. Dang ◽  
Tung T. Nguyen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Metal Organic ◽  
Organic Framework

Cu-CPO-27 was used as an efficient recyclable catalyst for the synthesis of benzothiazole–carbamate structures.

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