scholarly journals Hydrolysis of organometallic and metal–amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles

2018 ◽  
Vol 47 (11) ◽  
pp. 3638-3662 ◽  
Author(s):  
J. A. Garden ◽  
S. D. Pike

Organometallic and metal amide reagents react with –OH groups to generate metal–oxygen connectivity, yielding metal-oxo heterobimetallics, clusters and nanoparticles.

RSC Advances ◽  
2021 ◽  
Vol 11 (54) ◽  
pp. 33905-33915
Author(s):  
Julian Klein ◽  
Laura Kampermann ◽  
Sascha Saddeler ◽  
Jannik Korte ◽  
Oliver Kowollik ◽  
...  

CoxFe3−xO4 (0.4 < x < 2.5) nanoparticles show a broad green emission induced by surface OH-groups with a lower stability regarding UV-photoinduced dehydroxylation on Fe-rich (x ≤ 1.6) nanoparticles.


Author(s):  
Sagadevan Suresh ◽  
Selvaraj Vennila ◽  
J. Anita Lett ◽  
Is Fatimah ◽  
Faruq Mohammad ◽  
...  

2021 ◽  
Vol 23 (8) ◽  
Author(s):  
Eliecer Peláez Sifonte ◽  
Fidel Antonio Castro-Smirnov ◽  
Argenis Adrian Soutelo Jimenez ◽  
Héctor Raúl González Diez ◽  
Fernando Guzmán Martínez

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
N. C. Angastiniotis ◽  
S. Christopoulos ◽  
K. C. Petallidou ◽  
A. M. Efstathiou ◽  
A. Othonos ◽  
...  

AbstractA bulk scale process is implemented for the production of nanostructured film composites comprising unary or multi-component metal oxide nanoparticles dispersed in a suitable polymer matrix. The as-received nanoparticles, namely Al$$_2$$ 2 O$$_3$$ 3 , SiO$$_2$$ 2 and TiO$$_2$$ 2 and binary combinations, are treated following specific chemical and mechanical processes in order to be suspended at the optimal size and composition. Subsequently, a polymer extrusion technique is employed for the fabrication of each film, while the molten polymer is mixed with the treated metal oxide nanoparticles. Transmission and reflection measurements are performed in order to map the optical properties of the fabricated, nanostructured films in the UV, VIS and IR. The results substantiate the capability of the overall methodology to regulate the optical properties of the films depending on the type of nanoparticle formation which can be adjusted both in size and composition.


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