Facile hydrogenation of N-heteroarenes by magnetic nanoparticle-supported sub-nanometric Rh catalysts in aqueous medium

2018 ◽  
Vol 8 (18) ◽  
pp. 4709-4717 ◽  
Author(s):  
M. Nasiruzzaman Shaikh ◽  
Md. Abdul Aziz ◽  
Abdul Nasar Kalanthoden ◽  
Aasif Helal ◽  
Abbas S. Hakeem ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Magnetic Nanoparticle ◽  
Heterogeneous Nanocatalyst

This work describes the preparation and systematic characterization of a reusable magnetic heterogeneous nanocatalyst (Rh@Fe3O4) for the hydrogenation of N-heterocycles and simple aromatics.

Synthesis and Characterization of Tris(trimethyltin) Thiophosphate (Me3Sn)3PO3S

1993 ◽  
Vol 48 (12) ◽  
pp. 1781-1783 ◽  
Author(s):  
Abdel-Fattah Shihada
Keyword(s):  
Aqueous Medium ◽  
Raman Spectra ◽  
Mass Spectra ◽  
Ir And Raman Spectra ◽  
Synthesis And Characterization ◽  
Polymeric Structure ◽  
Ir And Raman

(Me3Sn)3PO3S has been prepared from the reaction of Me3SnCl with Na3PO3S • 12 H2O under cooling in aqueous medium. Its IR and Raman spectra are found to be consistent with a polymeric structure with tetra- and penta-coordinated tin atoms. The 31P NMR and mass spectra of (Me3Sn)3PO3S are reported and discussed.

scholarly journals Synthesis and Characterization of Magnetic Nanoparticles (MNP) and MNP-Chitosan Composites

2019 ◽  
Author(s):  
Monica Namizie Asey ◽  
Norhaizan Mohd Esa ◽  
Che Azurahanim Che Abdullah
Keyword(s):  
Chemical Bonding ◽  
Magnetic Nanoparticle ◽  
Ftir Analysis ◽  
Optimum Size ◽  
Optimum Ratio ◽  
Anticancer Drug Delivery ◽  
The Common ◽  
Stretching Vibrations ◽  
Direct Toxicity

Coating of iron oxide nanoparticles (MNP) is the common approach to reduce the effects of direct toxicity due to the ion oxidation that lead to the damage of DNA. This study investigates the effect of different concentration of Chitosan (Cs) used to coat the magnetic nanoparticle with variation in the crystallite size, chemical bonding, changes in weight and surface morphology. From the XRD results, it shows that the sample 1MNP-1Cs has optimum size of 13.42 ± 0.01 nm. From the FTIR analysis, it is revealed that there are three types of chemical bonding that occur in the MNP-Cs composites which are stretching vibrations of C-H, N–H vibration belonging to Cs and the Fe-O bonds from the MNP. From the FESEM analysis, it is found that the MNP-Cs composites have a wellshaped with spherical in form, as well as, smooth surfaces. As for TGA, the thermal decomposition of MNP nanocomposites was based on the amount of Cs and MNP used to produce the nanocomposites. Further studies will be conducted to find the optimum ratio of MNP-Cs for anticancer drug delivery application.

scholarly journals Novel Benchtop Magnetic Particle Spectrometer for Process Monitoring of Magnetic Nanoparticle Synthesis

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2277
Author(s):  
Norbert Löwa ◽  
Dirk Gutkelch ◽  
Ernst-Albrecht Welge ◽  
Roland Welz ◽  
Florian Meier ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetic Nanoparticles ◽  
Process Monitoring ◽  
Magnetic Nanoparticle ◽  
Magnetic Particle ◽  
Nanoparticle Synthesis ◽  
Separation Processes ◽  
Magnetic Detector ◽  
Application Fields

Magnetic nanoparticles combine unique magnetic properties that can be used in a variety of biomedical applications for therapy and diagnostics. These applications place high demands on the magnetic properties of nanoparticles. Thus, research, development, and quality assurance of magnetic nanoparticles requires powerful analytical methods that are capable of detecting relevant structural and, above all, magnetic parameters. By directly coupling nanoparticle synthesis with magnetic detectors, relevant nanoparticle properties can be obtained and evaluated, and adjustments can be made to the manufacturing process in real time. This work presents a sensitive and fast magnetic detector for online characterization of magnetic nanoparticles during their continuous micromixer synthesis. The detector is based on the measurement of the nonlinear dynamic magnetic response of magnetic nanoparticles exposed to an oscillating excitation at a frequency of 25 kHz, a technique also known as magnetic particle spectroscopy. Our results underline the excellent suitability of the developed magnetic online detection for coupling with magnetic nanoparticle synthesis based on the micromixer approach. The proven practicability and reliability of the detector for process monitoring forms the basis for further application fields, e.g., as a monitoring tool for chromatographic separation processes.

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