Make room for iodine: systematic pore tuning of multivariate metal–organic frameworks for the catalytic oxidation of hydroquinones using hypervalent iodine

2018 ◽  
Vol 8 (17) ◽  
pp. 4349-4357 ◽  
Author(s):  
Babak Tahmouresilerd ◽  
Patrick J. Larson ◽  
Daniel K. Unruh ◽  
Anthony F. Cozzolino
Keyword(s):  
Pore Size ◽  
Catalytic Oxidation ◽  
Metal Organic Frameworks ◽  
Hypervalent Iodine ◽  
Multivariate Approach ◽  
Metal Organic ◽  
The Right

A multivariate approach has been to to establish the right balance between iodine loading and pore size for catalytic oxidative dearomatizations in MIL-53 (Al) and UiO-66 (Zr) MOFs.

Are you using the right probe molecules for assessing the textural properties of metal–organic frameworks?

2022 ◽  
Author(s):  
Timur Islamoglu ◽  
Karam B. Idrees ◽  
Florencia A. Son ◽  
Zhijie Chen ◽  
Seung-Joon Lee ◽  
...  
Keyword(s):  
Pore Size Distribution ◽  
Porous Materials ◽  
Pore Size ◽  
Size Distribution ◽  
Surface Area ◽  
Pore Volume ◽  
Metal Organic Frameworks ◽  
Textural Properties ◽  
Metal Organic ◽  
The Right

Textural properties—such as the surface area, pore size distribution, and pore volume—are at the forefront of characterization for porous materials.

scholarly journals Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal–Organic Frameworks

2018 ◽  
Vol 30 (22) ◽  
pp. 8332-8342 ◽  
Author(s):  
Darpandeep Aulakh ◽  
Timur Islamoglu ◽  
Veronica F. Bagundes ◽  
Juby R. Varghese ◽  
Kyle Duell ◽  
...  
Keyword(s):  
Pore Size ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Metal Organic

Pore Size Reduction in Zirconium Metal–Organic Frameworks for Ethylene/Ethane Separation

2019 ◽  
Vol 7 (7) ◽  
pp. 7118-7126 ◽  
Author(s):  
Yuxiang Wang ◽  
Shuai Yuan ◽  
Zhigang Hu ◽  
Tanay Kundu ◽  
Jian Zhang ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Size Reduction ◽  
Metal Organic ◽  
Zirconium Metal

scholarly journals Tailoring the pore geometry and chemistry in microporous metal–organic frameworks for high methane storage working capacity

2019 ◽  
Vol 55 (76) ◽  
pp. 11402-11405 ◽  
Author(s):  
Kai Shao ◽  
Jiyan Pei ◽  
Jia-Xin Wang ◽  
Yu Yang ◽  
Yuanjing Cui ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Pore Geometry ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

We realized that engineering the pore size/geometry and chemistry in a series of MOFs can optimize the volumetric methane storage working capacity.

scholarly journals Gas Sensing Properties of Mg-Incorporated Metal–Organic Frameworks

Sensors ◽  
2019 ◽  
Vol 19 (15) ◽  
pp. 3323 ◽  
Author(s):  
Jae-Hyoung Lee ◽  
Thanh-Binh Nguyen ◽  
Duy-Khoi Nguyen ◽  
Jae-Hun Kim ◽  
Jin-Young Kim ◽  
...  
Keyword(s):  
Pore Size ◽  
Gas Sensors ◽  
Gas Sensing ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
Kinetic Properties ◽  
Sensing Properties ◽  
Sensing Applications ◽  
Gas Sensing Properties ◽  
Metal Organic

The gas sensing properties of two novel series of Mg-incorporated metal–organic frameworks (MOFs), termed Mg-MOFs-I and -II, were assessed. The synthesized iso-reticular type Mg-MOFs exhibited good crystallinity, high thermal stability, needle-shape morphology and high surface area (up to 2900 m2·g−1), which are promising for gas sensing applications. Gas-sensing studies of gas sensors fabricated from Mg-MOFs-II revealed better sensing performance, in terms of the sensor dynamics and sensor response, at an optimal operating temperature of 200 °C. The MOF gas sensor with a larger pore size and volume showed shorter response and recovery times, demonstrating the importance of the pore size and volume on the kinetic properties of MOF-based gas sensors. The gas-sensing results obtained in this study highlight the potential of Mg-MOFs gas sensors for the practical monitoring of toxic gases in a range of environments.

Pore Size Reduction by Methyl Function in Aluminum-Based Metal–Organic Frameworks for Xenon/Krypton Separation

2020 ◽  
Vol 20 (12) ◽  
pp. 8039-8046
Author(s):  
Zhaotong Yan ◽  
Youjin Gong ◽  
Chu-Ting Yang ◽  
Xiaonan Wu ◽  
Boyu Liu ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Size Reduction ◽  
Metal Organic

Salt nanoconfinement in zirconium-based metal–organic frameworks leads to pore-size and loading-dependent ionic conductivity enhancement

2020 ◽  
Vol 56 (53) ◽  
pp. 7245-7248
Author(s):  
Sorout Shalini ◽  
Thomas P. Vaid ◽  
Adam J. Matzger
Keyword(s):  
Ionic Conductivity ◽  
Pore Size ◽  
Metal Organic Frameworks ◽  
Significant Enhancement ◽  
Conductivity Enhancement ◽  
Metal Organic ◽  
Novel Method ◽  
Ion Conductors

Confinement of the salt [NEt4][TFSI] in metal–organic frameworks leads to a significant enhancement in ionic conductivity, pointing toward a novel method of creating solid ion conductors.

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