Modifying the sensibility of nonmetal-doped phosphorene by local or global properties

2019 ◽  
Vol 21 (9) ◽  
pp. 4899-4906 ◽  
Author(s):  
Na Yang ◽  
Li Li ◽  
Jing Li ◽  
Zidong Wei
Keyword(s):  
Charge Transfer ◽  
Electronic Properties ◽  
Dopant Atom ◽  
Global Properties ◽  
Adsorption Species

The dopant atom X can modify the sensibility of X-doped phosphorene by tuning the electronic properties of X-doped phosphorene surfaces effectively. According to the adsorption strength and the amount of charge transfer between the adsorption species and X-doped phosphorene surfaces, the adsorption species can be roughly divided into three types.

Growth direction dependent separate-channel charge transport in organic weak charge-transfer co-crystal of anthracene-DTTCNQ

2022 ◽  
Author(s):  
Hui Jiang ◽  
Jun Ye ◽  
Peng Hu ◽  
Shengli Zhu ◽  
Yanqin Liang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transport ◽  
Electronic Properties ◽  
Single Crystals ◽  
Organic Semiconductors ◽  
Crystal Engineering ◽  
Molecular Crystal ◽  
Growth Direction ◽  
Weak Charge ◽  
Separate Channel

Co-crystallization is an efficient way of molecular crystal engineering to tune the electronic properties of organic semiconductors. In this work, we synthesized anthracene-4,8-bis(dicyanomethylene)4,8-dihydrobenzo[1,2-b:4,5-b’]-dithiophene (DTTCNQ) single crystals as a template to...

scholarly journals Rich p -type-doping phenomena in boron-substituted silicene systems

2020 ◽  
Vol 7 (12) ◽  
pp. 200723
Author(s):  
Hai Duong Pham ◽  
Wu-Pei Su ◽  
Thi Dieu Hien Nguyen ◽  
Ngoc Thanh Thuy Tran ◽  
Ming-Fa Lin
Keyword(s):  
Charge Transfer ◽  
Fermi Level ◽  
Charge Density ◽  
Electronic Properties ◽  
First Principles ◽  
Chemical Environment ◽  
First Principles Calculations ◽  
Density Distributions ◽  
Essential Properties ◽  
P Type

The essential properties of monolayer silicene greatly enriched by boron substitutions are thoroughly explored through first-principles calculations. Delicate analyses are conducted on the highly non-uniform Moire superlattices, atom-dominated band structures, charge density distributions and atom- and orbital-decomposed van Hove singularities. The hybridized 2 p z –3 p z and [2s, 2 p x , 2 p y ]–[3s, 3 p x , 3 p y ] bondings, with orthogonal relations, are obtained from the developed theoretical framework. The red-shifted Fermi level and the modified Dirac cones/ π bands/ σ bands are clearly identified under various concentrations and configurations of boron-guest atoms. Our results demonstrate that the charge transfer leads to the non-uniform chemical environment that creates diverse electronic properties.

scholarly journals An overview of the cycloaddition chemistry of fulvenes and emerging applications

2019 ◽  
Vol 15 ◽  
pp. 2113-2132
Author(s):  
Ellen Swan ◽  
Kirsten Platts ◽  
Anton Blencowe
Keyword(s):  
Natural Products ◽  
Charge Transfer ◽  
Electronic Properties ◽  
Combinatorial Chemistry ◽  
Low Temperatures ◽  
Charge Transfer Complexes ◽  
Reference Source ◽  
Materials Chemistry ◽  
Dynamic Combinatorial Chemistry ◽  
Cyclic Adducts

The unusual electronic properties and unique reactivity of fulvenes have interested researchers for over a century. The propensity to form dipolar structures at relatively low temperatures and to participate as various components in cycloaddition reactions, often highly selectively, makes them ideal for the synthesis of complex polycyclic carbon scaffolds. As a result, fulvene cycloaddition chemistry has been employed extensively for the synthesis of natural products. More recently, fulvene cycloaddition chemistry has also found application to other areas including materials chemistry and dynamic combinatorial chemistry. This highlight article discusses the unusual properties of fulvenes and their varied cycloaddition chemistry, focussing on applications in organic and natural synthesis, dynamic combinatorial chemistry and materials chemistry, including dynamers, hydrogels and charge transfer complexes. Tables providing comprehensive directories of fulvene cycloaddition chemistry are provided, including fulvene intramolecular and intermolecular cycloadditions complete with reactant partners and their resulting cyclic adducts, which provide a useful reference source for synthetic chemists working with fulvenes and complex polycyclic scaffolds.

scholarly journals Reply to Comment on Polymorphism in the 1:1 Charge-Transfer Complex DBTTF-TCNQ and Its Effects on Optical and Electronic Properties

2017 ◽  
Vol 3 (3) ◽  
pp. 1600521 ◽  
Author(s):  
Katelyn P. Goetz ◽  
Jun'ya Tsutsumi ◽  
Sujitra Pookpanratana ◽  
Jihua Chen ◽  
Nathan S. Corbin ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Electronic Properties ◽  
Charge Transfer Complex ◽  
Optical And Electronic Properties

scholarly journals Electronic properties of Fabre charge-transfer salts under various temperature and pressure conditions

2013 ◽  
Vol 87 (15) ◽  
Author(s):  
A. C. Jacko ◽  
H. Feldner ◽  
E. Rose ◽  
F. Lissner ◽  
M. Dressel ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Electronic Properties ◽  
Charge Transfer Salts ◽  
Temperature And Pressure
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