Nanoporous gold functionalized with praseodymia–titania mixed oxides as a stable catalyst for the water–gas shift reaction

2019 ◽  
Vol 21 (6) ◽  
pp. 3278-3286 ◽  
Author(s):  
Junjie Shi ◽  
Arne Wittstock ◽  
Christoph Mahr ◽  
M. Mangir Murshed ◽  
Thorsten M. Gesing ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Mixed Oxides ◽  
Nanoporous Gold ◽  
Water Gas Shift ◽  
Great Promise ◽  
Water Gas Shift Reaction ◽  
Nanoporous Metals ◽  
Inverse Catalyst ◽  
Shift Reaction ◽  
Water Gas

Dealloyed nanoporous metals hold great promise in the field of heterogeneous catalysis. In our work, we succeeded to prepare a stable and very active inverse catalyst for the water gas shift reaction by depositing Pr1Ti2Ox on nanoporous gold.

scholarly journals A versatile sol–gel coating for mixed oxides on nanoporous gold and their application in the water gas shift reaction

2016 ◽  
Vol 6 (14) ◽  
pp. 5311-5319 ◽  
Author(s):  
Junjie Shi ◽  
Christoph Mahr ◽  
M. Mangir Murshed ◽  
Volkmar Zielasek ◽  
Andreas Rosenauer ◽  
...  
Keyword(s):  
Mixed Oxides ◽  
Sol Gel ◽  
Nanoporous Gold ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Highly Active ◽  
Shift Reaction ◽  
Water Gas

Ceria–titania mixed oxides on a structured nanoporous gold support result in highly active and durable catalysts for the water-gas shift reaction.

Praseodymium hydroxide/gold-supported precursor: a new strategy for preparing stable and active catalyst for the water-gas shift reaction

2020 ◽  
Vol 10 (21) ◽  
pp. 7291-7301
Author(s):  
Junjie Shi ◽  
Hailian Li ◽  
Weixuan Zhao ◽  
Pengfei Qi ◽  
Hongxin Wang
Keyword(s):  
Heterogeneous Catalysis ◽  
High Activity ◽  
Active Catalyst ◽  
Water Gas Shift ◽  
Great Promise ◽  
Water Gas Shift Reaction ◽  
New Strategy ◽  
O Vacancy ◽  
Shift Reaction ◽  
Water Gas

Rod-shaped praseodymium hydroxide (Pr(OH)x) as a hydroxyl- and O vacancy-rich support can promote the dispersion and stabilization of Au species show high activity and stability for water gas shift reaction, and holds great promise in the field of heterogeneous catalysis.

Effect of the Ration of Cu to Mn on the Activity and Stability of Copper-Manganese Mixed-Oxides for the Water Gas Shift Reaction

2013 ◽  
Vol 634-638 ◽  
pp. 518-521 ◽  
Author(s):  
Ke Duan Zhi ◽  
Quan Sheng Liu ◽  
Run Xia He ◽  
Fang Wu ◽  
Ya Gang Zhang ◽  
...  
Keyword(s):  
Surface Area ◽  
Mixed Oxides ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Catalyst Structure ◽  
Catalytic Behavior ◽  
Stable Catalyst ◽  
Copper Manganese ◽  
Shift Reaction ◽  
Water Gas

The effects of Cu/Mn ratio on the activity and stability of Cu-Mn catalysts for the water-gas shift reaction (WGSR) were investigated. Activity tests showed that the Cu-Mn catalyst while the ration of Cu to Mn is 1:1 displayed higher activity and better stability than that of others catalysts. The BET , XRD and TPR results revealed that the Cu-Mn catalyst while the ration of Cu to Mn is 1:1 led to higher surface area, a more stable catalyst structure and suitable reduction performance, in turn leading to better catalytic behavior for the Cu-Mn catalyst.

Water gas shift reaction over Cu–Mn mixed oxides catalysts: Effects of the third metal

2008 ◽  
Vol 89 (2) ◽  
pp. 131-138 ◽  
Author(s):  
Xiaru Du ◽  
Zhongshan Yuan ◽  
Lei Cao ◽  
Chunxi Zhang ◽  
Shudong Wang
Keyword(s):  
Mixed Oxides ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
The Third ◽  
Shift Reaction ◽  
Water Gas

Copper-Based Mixed Oxides Catalyst of Water-Gas Shift Reaction for Fuel Cells: The Role of Alkali Charge

2012 ◽  
Vol 268-270 ◽  
pp. 538-541
Author(s):  
Ke Duan Zhi ◽  
Quan Sheng Liu ◽  
Run Xia He ◽  
Fang Wu ◽  
Ya Gang Zhang ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Surface Area ◽  
Mixed Oxides ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Catalyst Structure ◽  
Catalytic Behavior ◽  
Shift Reaction ◽  
Water Gas

The effects of alkali charge on the activity and stability of copper-based mixed oxides catalyst for the water-gas shift reaction (WGSR) were investigated. Activity tests showed that the copper-based mixed oxides catalyst while the 2[NaOH]/[Cu2++Mn2+] is above 1.2 displayed higher activity and better stability than that of others catalysts. The BET , XRD and TPR results revealed that the Cu-Mn catalyst while the 2[NaOH]/[Cu2++Mn2+] is above 1.2 led to higher surface area, a more stable catalyst structure and suitable reduction performance, in turn leading to better catalytic behavior for the Cu-Mn catalyst.

scholarly journals Ce–Mn mixed oxides as supports of copper- and nickel-based catalysts for water–gas shift reaction

2014 ◽  
Vol 119 ◽  
pp. 67-73 ◽  
Author(s):  
Eduardo Poggio Fraccari ◽  
Oriana D’Alessandro ◽  
Jorge Sambeth ◽  
Graciela Baronetti ◽  
Fernando Mariño
Keyword(s):  
Mixed Oxides ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Shift Reaction ◽  
Water Gas

Water gas shift reaction over Cu-based mixed oxides for CO removal from the reformed fuels

2003 ◽  
Vol 242 (2) ◽  
pp. 287-295 ◽  
Author(s):  
Yohei Tanaka ◽  
Toshimasa Utaka ◽  
Ryuji Kikuchi ◽  
Kazunari Sasaki ◽  
Koichi Eguchi
Keyword(s):  
Mixed Oxides ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Co Removal ◽  
Shift Reaction ◽  
Water Gas

Study of the water-gas shift reaction over Pt supported on CeO2–ZrO2 mixed oxides

2011 ◽  
Vol 171 (1) ◽  
pp. 297-303 ◽  
Author(s):  
C.I. Vignatti ◽  
M.S. Avila ◽  
C.R. Apesteguía ◽  
T.F. Garetto
Keyword(s):  
Mixed Oxides ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Shift Reaction ◽  
Water Gas
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