Temperature dependence of photophysical properties of a dinuclear C^N-cyclometalated Pt(ii) complex with an intimate Pt–Pt contact. Zero-field splitting and sub-state decay rates of the lowest triplet

2018 ◽  
Vol 20 (38) ◽  
pp. 25096-25104 ◽  
Author(s):  
Joseph C. Deaton ◽  
Arnab Chakraborty ◽  
Rafal Czerwieniec ◽  
Hartmut Yersin ◽  
Felix N. Castellano
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Photophysical Properties ◽  
Decay Rates ◽  
Zero Field ◽  
Triplet Excited State ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Ligand Charge Transfer ◽  
Metal Metal

A dinuclear Pt(ii) complexes exhibits an unusually large zero field splitting in its metal–metal-to-ligand charge transfer triplet excited state.

Zero-field splitting of the ligand-ligand charge-transfer emitting manifold of zinc(II) complexes

1991 ◽  
Vol 95 (22) ◽  
pp. 8538-8541 ◽  
Author(s):  
Shigeru Ikeda ◽  
Seiichi Yamamoto ◽  
Kaoru Nozaki ◽  
Takeshi Ikeyama ◽  
Tohru Azumi ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Ligand Charge Transfer

Interplay of Zero-Field Splitting and Excited State Geometry Relaxation in fac-Ir(ppy)3

2015 ◽  
Vol 54 (21) ◽  
pp. 10457-10461 ◽  
Author(s):  
José P. Gonzalez-Vazquez ◽  
Paul L. Burn ◽  
Benjamin J. Powell
Keyword(s):  
Excited State ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting
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