Exploring the electronic structure of aluminum metal–organic framework Basolite A100: solid-state synchronous fluorescence spectroscopy reveals new charge excitation/relaxation pathways

2018 ◽  
Vol 20 (42) ◽  
pp. 26947-26956 ◽  
Author(s):  
Cole Grinnell ◽  
Alexander Samokhvalov
Keyword(s):  
Electronic Structure ◽  
Solid State ◽  
Fluorescence Spectroscopy ◽  
Metal Organic Framework ◽  
Synchronous Fluorescence ◽  
Synchronous Fluorescence Spectroscopy ◽  
Aluminum Metal ◽  
Metal Organic ◽  
Organic Framework

Solid-state synchronous fluorescence spectroscopy is superior to “conventional” fluorescence; it identifies absorption/emission by the linkers, bandgap and excimers in Al-MOF Basolite A100.

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

scholarly journals Impact of nanosizing a host matrix based on a metal–organic framework on solid-state fluorescence emission and energy transfer

2022 ◽  
Author(s):  
Hikaru Sakamoto ◽  
Akitaka Ito ◽  
Masataka Ohtani
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Metal Organic Framework ◽  
Fluorescence Emission ◽  
Dye Molecules ◽  
Host Matrix ◽  
Metal Organic ◽  
Solid State Fluorescence ◽  
Organic Framework

We demonstrate that the nanosize effect appears to affect the properties of dye molecules encapsulated in the pores of a metal–organic framework (dye@MOF). The emissive properties of the nanosized dye@MOF...

A post-synthetic approach triggers selective and reversible sulphur dioxide adsorption on a metal–organic framework

2018 ◽  
Vol 54 (65) ◽  
pp. 9063-9066 ◽  
Author(s):  
Marta Mon ◽  
Estefanía Tiburcio ◽  
Jesús Ferrando-Soria ◽  
Rodrigo Gil San Millán ◽  
Jorge A. R. Navarro ◽  
...  
Keyword(s):  
Solid State ◽  
Cation Exchange ◽  
Sulphur Dioxide ◽  
Metal Organic Framework ◽  
Exchange Process ◽  
Synthetic Approach ◽  
Metal Organic ◽  
Organic Framework

We report the application of a post-synthetic solid-state cation-exchange process to afford a novel 3D MOF with hydrated barium cations hosted at pores able to trigger selective and reversible SO2adsorption.

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