Atmospheric chemistry of (Z)-CF3CHCHCl: products and mechanisms of the Cl atom, OH radical and O3 reactions, and role of (E)–(Z) isomerization

2018 ◽  
Vol 20 (44) ◽  
pp. 27949-27958
Author(s):  
Mads P. Sulbaek Andersen ◽  
Theis I. Sølling ◽  
Lene Løffler Andersen ◽  
Aleksandra Volkova ◽  
Dvien Hovanessian ◽  
...  
Keyword(s):  
Ab Initio ◽  
Atmospheric Chemistry ◽  
Oh Radical ◽  
Chamber Studies ◽  
Cl Atom

Chamber studies and G4MP2 ab initio calculations investigate isomerization in the OH radical, Cl-atom and O3 initiated oxidation of (Z)-CF3CHCHCl.

Atmospheric chemistry of CF3CFCH2: Products and mechanisms of Cl atom and OH radical initiated oxidation

2008 ◽  
Vol 450 (4-6) ◽  
pp. 263-267 ◽  
Author(s):  
M.D. Hurley ◽  
T.J. Wallington ◽  
M.S. Javadi ◽  
O.J. Nielsen
Keyword(s):  
Atmospheric Chemistry ◽  
Oh Radical ◽  
Cl Atom

Atmospheric Chemistry of Perfluorinated Aldehyde Hydrates (n-CxF2x+1CH(OH)2,x= 1, 3, 4):  Hydration, Dehydration, and Kinetics and Mechanism of Cl Atom and OH Radical Initiated Oxidation

2006 ◽  
Vol 110 (32) ◽  
pp. 9854-9860 ◽  
Author(s):  
M. P. Sulbaek Andersen ◽  
A. Toft ◽  
O. J. Nielsen ◽  
M. D. Hurley ◽  
T. J. Wallington ◽  
...  
Keyword(s):  
Atmospheric Chemistry ◽  
Kinetics And Mechanism ◽  
Oh Radical ◽  
Cl Atom

scholarly journals Atmospheric chemistry of trans-CF<sub>3</sub>CH=CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation

2008 ◽  
Vol 8 (1) ◽  
pp. 1069-1088
Author(s):  
M. S. Javadi ◽  
R. Søndergaard ◽  
O. J. Nielsen ◽  
M. D. Hurley ◽  
T. J. Wallington
Keyword(s):  
Environmental Impact ◽  
Hydroxyl Radical ◽  
Partial Pressure ◽  
Chlorine Atom ◽  
Atmospheric Chemistry ◽  
Oh Radical ◽  
Smog Chamber ◽  
O2 Partial Pressure ◽  
Cl Atom

Abstract. Smog chamber/FTIR techniques were used to study the products and mechanisms of OH radical and Cl atom initiated oxidation of trans-CF3CH=CHF in 700 Torr of N2/O2 diluent at 295±1 K. Hydroxyl radical initiated oxidation leads to the formation of CF3CHO and HC(O)F in yields which were indistinguishable from 100% and were not dependent on the O2 partial pressure. Chlorine atom initiated oxidation gives HC(O)F, CF3CHO, CF3C(O)Cl, and CF3C(O)CHFCl. The yields of CF3C(O)Cl and CF3C(O)CHFCl increased at the expense of HC(O)F and CF3CHO as the O2 partial pressure was increased over the range 5–700 Torr. The results are discussed with respect to the atmospheric chemistry and environmental impact of trans-CF3CH=CHF.

Atmospheric Chemistry of 3-Pentanol: Kinetics, Mechanisms, and Products of Cl Atom and OH Radical Initiated Oxidation in the Presence and Absence of NOX

2008 ◽  
Vol 112 (35) ◽  
pp. 8053-8060 ◽  
Author(s):  
M. D. Hurley ◽  
T. J. Wallington ◽  
M. Bjarrum ◽  
M. S. Javadi ◽  
O. J. Nielsen
Keyword(s):  
Atmospheric Chemistry ◽  
Oh Radical ◽  
Presence And Absence ◽  
Cl Atom

Atmospheric Chemistry of CH3CHF2(HFC-152a):  Kinetics, Mechanisms, and Products of Cl Atom- and OH Radical-Initiated Oxidation in the Presence and Absence of NOx

2005 ◽  
Vol 109 (40) ◽  
pp. 9061-9069 ◽  
Author(s):  
Fumikazu Taketani ◽  
Tomoki Nakayama ◽  
Kenshi Takahashi ◽  
Yutaka Matsumi ◽  
Michael D. Hurley ◽  
...  
Keyword(s):  
Atmospheric Chemistry ◽  
Oh Radical ◽  
Presence And Absence ◽  
Cl Atom ◽  
Hfc 152A

Atmospheric Chemistry of CF3CH2CH2OH:  Kinetics, Mechanisms and Products of Cl Atom and OH Radical Initiated Oxidation in the Presence and Absence of NOX

2005 ◽  
Vol 109 (43) ◽  
pp. 9816-9826 ◽  
Author(s):  
Michael D. Hurley ◽  
Jessica A. Misner ◽  
James C. Ball ◽  
Timothy J. Wallington ◽  
D. A. Ellis ◽  
...  
Keyword(s):  
Atmospheric Chemistry ◽  
Oh Radical ◽  
Presence And Absence ◽  
Cl Atom
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