scholarly journals Theoretical investigations on hydrogen peroxide decomposition in aquo

2018 ◽  
Vol 20 (38) ◽  
pp. 24992-24999 ◽  
Author(s):  
Takao Tsuneda ◽  
Tetsuya Taketsugu
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Oh Radical ◽  
Iron Ions ◽  
Hydrogen Bond Network ◽  
Iron Ion ◽  
Hydrogen Peroxide Decomposition ◽  
Peroxide Decomposition ◽  
Theoretical Investigations ◽  
Bond Network

Hydrogen peroxide (H2O2) decomposition mechanisms in the absence and presence of iron ions in aqueous solution, which contain no OH radical formation, are theoretically determined. H2O2 decomposition in the presence of iron ions is driven by electron transfer to the iron ion and proceeds by hydrogen transfers in the hydrogen bond network around H2O2.

Reply to the ‘Comment on “Theoretical investigations on hydrogen peroxide decomposition in aquo”’ by W. H. Koppenol, Phys. Chem. Chem. Phys., 2021, 23, DOI: 10.1039/D1CP03545B

2021 ◽  
Author(s):  
Takao Tsuneda ◽  
Tetsuya Taketsugu
Keyword(s):  
Hydrogen Peroxide ◽  
Decomposition Reaction ◽  
Chem Phys ◽  
Simple Test ◽  
Ion Hydration ◽  
Hydrogen Peroxide Decomposition ◽  
Gibbs Energies ◽  
Peroxide Decomposition ◽  
Theoretical Investigations ◽  
Phys Chem Chem Phys

The H2O2 decomposition reaction mechanism based on the production of a de facto Fe+ ion hydration complex is strongly supported by a simple test based on the Gibbs energies considering the O–O bond dissociation of H2O2.

scholarly journals OXIDATION OF FERRIC XYLENOL ORANGE CHELATES BY HYDROGEN PEROXIDE IN AQUEOUS SOLUTION: CONCEPTION OF OXYGEN SINGLET ATOMS GENERATION FROM HYDROGEN PEROXIDE

2018 ◽  
Vol 61 (2) ◽  
pp. 15
Author(s):  
Anton A. Chumakov ◽  
Oleg A. Kotelnikov ◽  
Yuriy G. Slizhov
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Ferric Iron ◽  
Xylenol Orange ◽  
Oxygen Species ◽  
Iron Ions ◽  
Iron Ion ◽  
Radical Chain ◽  
Mechanism Of Interaction ◽  
Peroxide Molecule

We observed for the first time the reaction of oxidation of ferric xylenol orange chelates by hydrogen peroxide in aqueous solution. The reaction is accompanied with decoloration of the violet aqueous solution. Based on generally accepted conception, there is a process of free radical chain oxidation of indicator molecule in the solution. However, after investigating the final colorless solution by 1H NMR-spectroscopy we found the modified but not broken structure in which the initial hydrocarbon core remained mainly unchanged. We concluded that kind of reaction was an oxyfunctionalization by hydrogen peroxide versus free radical chain destruction. We argued steps of the reaction such as N-oxidation, Cope’s elimination, and certain rearrangements with possible products oligomerization. There was a need to explain the mechanism of interaction between the ferric iron ion and the hydrogen peroxide molecule and to argue the nature of intermediate reactive oxygen species. There is similarity between the ferric-catalyzed hydroperoxide xylenol orange oxidation and the peroxygenase-catalyzed biochemical oxyfunctionalization reactions. However, based on literature data and molecular orbital modeling, we proposed another mechanism of interaction between the ferric iron ion and the hydrogen peroxide molecule instead the tetravalent iron generation. Concretely, we proposed the hydrogen peroxide zwitter-ionization (isomerization to oxywater molecule) and subsequent intramolecular disproportionation with generation of a water molecule and a singlet oxygen atom as a reactive oxygen species. In this view, the iron ion oxidation state is unchanged during the reaction and remains ferric. An oxyfunctionalization of any organic substrate by hydrogen peroxide in the presence of ferric iron ions is promising approach in organic synthesis. However, the usage of organic ligands for ferric iron ions as components of catalysts is limited and requires only non-oxidizable compounds. On the other hand, one can choose an oxidation substrate as a ligand for ferric iron ions that is the formation of chelate complex of ferric catalyst with an organic substrate.Forcitation:Chumakov A.A., Kotelnikov O.A., Slizhov Yu.G. Oxidation of ferric xylenol orange chelates by hydrogen peroxide in aqueous solution: conception of oxygen singlet atoms generation from hydrogen peroxide. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2018. V. 61. N 2. P. 15-22

Sign in / Sign up

Export Citation Format

Share Document