scholarly journals Reaction kinetics of OH + HNO3 under conditions relevant to the upper troposphere/lower stratosphere

2018 ◽  
Vol 20 (38) ◽  
pp. 24652-24664 ◽  
Author(s):  
Frank A. F. Winiberg ◽  
Carl J. Percival ◽  
Robin Shannon ◽  
M. Anwar H. Khan ◽  
Dudley E. Shallcross ◽  
...  

Key upper atmosphere reaction of HNO3 + OH studied over extended pressure and temperature range using new alternative detection method.

2019 ◽  
Vol 45 ◽  
pp. 146867831989141
Author(s):  
Bahador Abolpour ◽  
Rahim Shamsoddini

The reaction kinetics of carbon reduction of silica were investigated using thermodynamic concepts and by fitting to relevant models the experimental data obtained for this reduction using a thermogravimetric unit in the temperature range of 1566 to 1933 K. The results show that the only way to produce SiC in this reduction is the reaction of Si, SiO, or SiO2 at the surface or by diffusion of SiO inside the carbon particles while CO and CO2 have no direct effect on the process. The controlling step of this reduction at temperatures lower than 1750 K is the chemical gas–solid or solid–solid reaction at the surface of the carbon particles, while at higher temperatures, the rate of SiO diffusing inside the carbon particles controls the rate of this reduction.


2015 ◽  
Vol 120 (9) ◽  
pp. 1330-1346 ◽  
Author(s):  
J. C. Gómez Martín ◽  
S. A. Garraway ◽  
J. M. C. Plane

2017 ◽  
Vol 19 (10) ◽  
pp. 7147-7157 ◽  
Author(s):  
Fethi Khaled ◽  
Binod Raj Giri ◽  
Milán Szőri ◽  
Tam V.-T. Mai ◽  
Lam K. Huynh ◽  
...  

The reaction kinetics of dimethyl carbonate (DMC) and OH radicals were investigated behind reflected shock waves over the temperature range of 872–1295 K and at pressures near 1.5 atm.


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