scholarly journals Fragmentation of a dioxolanyl radical via nonstatistical reaction dynamics: characterization of the vinyloxy radical by ns time-resolved laser flash photolysis

2018 ◽  
Vol 20 (30) ◽  
pp. 19819-19828
Author(s):  
Götz Bucher ◽  
Mukul Lal ◽  
Anup Rana ◽  
Michael Schmittel
Keyword(s):  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Reaction Dynamics ◽  
Laser Flash ◽  
Time Resolved

Photolysis of a dioxolanyl Barton ester results in formation of the vinyloxy radical, via nonstatistical reaction dynamics. The nonstatistical reaction involves ester cleavage, CO2 loss and fragmentation of the intermediate dioxolanyl radical.

Structures of Reactive Nitrenium Ions:  Time-Resolved Infrared Laser Flash Photolysis and Computational Studies of SubstitutedN-Methyl-N-arylnitrenium Ions

2000 ◽  
Vol 122 (34) ◽  
pp. 8271-8278 ◽  
Author(s):  
Sanjay Srivastava ◽  
Patrick H. Ruane ◽  
John P. Toscano ◽  
Michael B. Sullivan ◽  
Christopher J. Cramer ◽  
...  
Keyword(s):  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Infrared Laser ◽  
Computational Studies ◽  
Time Resolved ◽  
Nitrenium Ions ◽  
Arylnitrenium Ions

scholarly journals Kinetic studies of C1 and C2 Criegee intermediates with SO2 using laser flash photolysis coupled with photoionization mass spectrometry and time resolved UV absorption spectroscopy

2018 ◽  
Vol 20 (34) ◽  
pp. 22218-22227 ◽  
Author(s):  
N. U. M. Howes ◽  
Z. S. Mir ◽  
M. A. Blitz ◽  
S. Hardman ◽  
T. R. Lewis ◽  
...  
Keyword(s):  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Kinetic Studies ◽  
Laser Flash ◽  
Major Product ◽  
Time Resolved ◽  
Photoionization Mass Spectrometry ◽  
Criegee Intermediates ◽  
Wide Range ◽  
Kinetics Of

Kinetics of CH2OO + SO2 confirmed over a wide range of [SO2]. Acetaldehyde observed as a major product of the reaction of CH3CHOO + SO2.

Photochemistry of triphenylamine (TPA) in homogeneous solution and the role of transient N-phenyl-4a,4b-dihydrocarbazole. A steady-state and time-resolved investigation.

2021 ◽  
Author(s):  
Stefano Protti ◽  
Mariella Mella ◽  
Sergio Mauricio Bonesi
Keyword(s):  
Steady State ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Homogeneous Solution ◽  
Laser Flash ◽  
Time Resolved ◽  
Homogeneous Media

Abstract. The photoreactivity of triphenylamine in homogeneous media has been investigated by means of laser flash photolysis spectroscopy and preparative experiments. The goal of this study consists in the evaluation...

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