The influence of aggregation on the third-order nonlinear optical property of π-conjugated chromophores: the case of cyanine dyes

2018 ◽  
Vol 20 (24) ◽  
pp. 16777-16785 ◽  
Author(s):  
Chao Wang ◽  
Yizhong Yuan
Keyword(s):  
Optical Property ◽  
Nonlinear Optical ◽  
Nonlinear Optical Property ◽  
Cyanine Dyes ◽  
Photon Absorption ◽  
Third Order ◽  
Two Photon Absorption ◽  
Two Photon ◽  
The Third ◽  
Potential Applications

The typical J cyanine aggregate is experimentally and theoretically found to have potential applications involving two photon absorption.

THIRD-ORDER NONLINEAR OPTICAL PROPERTY OF POLY(HEXA-2,4-DIYNYLENE-1,6-DIOXYDICINNAMATE) CONTAINING A POLAR AZO DYE, DETERMINED BY Z-SCAN TECHNIQUE

2009 ◽  
Vol 18 (01) ◽  
pp. 161-166 ◽  
Author(s):  
ALEJANDRA ORTEGA ◽  
ANA LAURA PEREZ-MARTINEZ ◽  
TAKESHI OGAWA ◽  
FRANCIS SMITH ◽  
ARDIE WALSER ◽  
...  
Keyword(s):  
Azo Dye ◽  
Nonlinear Optical ◽  
Nonlinear Optical Property ◽  
Photon Absorption ◽  
Nonlinear Susceptibility ◽  
Aromatic Rings ◽  
Third Order ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Third Order Nonlinear Susceptibility

A highly-conjugated polar dye with three aromatic rings connected with azo groups was prepared and it was incorporated in polycinnamate. It showed a third-order nonlinear susceptibility of 8 × 10-10 esu determined by a Z-scan technique. The unpoled and poled films show the same susceptibility indicating the polymer film could not be poled. The open aperture Z-scan showed negligible two-photon absorption at 1064 nm.

scholarly journals Giant Third-Order Nonlinear Response of Mixed Perovskite Nanocrystals

Materials ◽  
2022 ◽  
Vol 15 (1) ◽  
pp. 389
Author(s):  
Aya M. Abu Baker ◽  
Ganjaboy S. Boltaev ◽  
Mazhar Iqbal ◽  
Mikhail Pylnev ◽  
Nasser M. Hamdan ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Laser Pulses ◽  
Photon Absorption ◽  
Third Order ◽  
Central Wavelength ◽  
Third Harmonic ◽  
Perovskite Nanocrystals ◽  
Two Photon Absorption ◽  
Two Photon ◽  
The Third

Mixed (FAPbI3)0.92(MAPbBr3)0.08 perovskite thin films exhibit strong nonlinear optical responses, rendering them promising candidates for applications in photonics and optical communications. In this work, we present a systematic study on the ultrafast third-order nonlinear optical processes in mixed perovskite nanocrystals (NCs) by exploring the generation of third harmonic radiation and giant two-photon absorption-based photoluminescence (PL) when excited by femtosecond laser pulses of a 1030 nm central wavelength. A comparative analysis of the coherent third harmonic generation in the thin-film-containing perovskite nanocrystals has shown a 40× enhancement of the third harmonic signal compared to the signal generated in the pure quartz substrate. The cubic dependence of the third-nonlinear optical response of the (FAPbI3)0.92(MAPbBr3)0.08 perovskites on the intensity of the driving radiation was identified using broadband 38 femtosecond driving pulses. The positive nonlinear refractive index (γ = +1.4 × 10−12 cm2·W−1) is found to play an important role in improving the phase-matching conditions of the interacting pulses by generating a strong third order harmonic. The giant two-photon absorption (TPA)-assisted PL peak was monitored and a blue shift of the PL was obtained in the higher intensity range of the laser pulses, with the absorption coefficient β estimated to be~+7.0 cm·MW−1 at a 1030 nm laser wavelength.

Two-dimensional two-photon absorptions and third-order nonlinear optical properties of Ih fullerenes and fullerene onions

2020 ◽  
Vol 22 (25) ◽  
pp. 14225-14235
Author(s):  
Xue-Lian Zheng ◽  
Ling Yang ◽  
Bo Shang ◽  
Ming-Qian Wang ◽  
Yingli Niu ◽  
...  
Keyword(s):  
Optical Properties ◽  
Phase Modulation ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Photon Absorption ◽  
Two Dimensional ◽  
Third Order ◽  
Two Photon Absorption ◽  
Two Photon ◽  
The Third

The third order nonlinear optical properties of Ih symmetry fullerenes increase exponentially with fullerene size. The two-dimensional two-photon absorption spectra for C60 and C240 have strong self-phase modulation responses.

scholarly journals Tunable Nonlinear Optical Property of MnS Nanoparticles with Different Size and Crystal Form

Nanomaterials ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 34
Author(s):  
Zhihao Zhang ◽  
Pengchao Li ◽  
Yuzong Gu
Keyword(s):  
Optical Property ◽  
Nonlinear Optical ◽  
Nonlinear Optical Property ◽  
Nonlinear Refraction ◽  
Synthesis Method ◽  
Crystal Form ◽  
Optical Nonlinearity ◽  
Photon Absorption ◽  
Third Order ◽  
Crystal Forms

It is significant to study the reason that semiconductor material has adjustable third-order optical nonlinearity through crystal form and dimensions are changed. αMnS nanoparticles with different crystal forms and sizes were successfully prepared by one-step hydrothermal synthesis method and their size-limited third-order nonlinear optical property was tested by Z-scan technique with 30 ps laser pulses at 532 nm wavelength. Nanoparticles of different crystal forms exhibited different NLO (nonlinear optical) responses. γMnS had stronger NLO response than αMnS because of higher fluorescence quantum yield. Two-photon absorption and the nonlinear refraction are enhanced as size of nanoparticlesreduced. The nanoparticles had maximum NLO susceptibility which was 3.09 × 10−12 esu. Susceptibility of αMnS increased about nine times than that of largest nanoparticles. However, it was reduced when size was further decreased. This trend was explained by the effects of light induced dipole moments. And defects in αMnS nanoparticles also had effect on this nonlinear process. MnS nanoparticles had potential application value in optical limiting and optical modulation.

Third-order nonlinear optical properties and two-photon absorption in branched oligothienylenevinylenes

2002 ◽  
Vol 209 (4-6) ◽  
pp. 461-466 ◽  
Author(s):  
I. Fuks-Janczarek ◽  
J-M. Nunzi ◽  
B. Sahraoui ◽  
I.V. Kityk ◽  
J. Berdowski ◽  
...  
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Photon Absorption ◽  
Third Order ◽  
Two Photon Absorption ◽  
Two Photon

Third-order nonlinear optical properties and two-photon absorption in polymers doped withp-phenyl sydnone

2008 ◽  
Vol 108 (5) ◽  
pp. 3218-3224 ◽  
Author(s):  
Seetharam Shettigar ◽  
G. Umesh ◽  
K. Chandrasekharan ◽  
Ganesh Rai ◽  
B. Kalluraya
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Photon Absorption ◽  
Third Order ◽  
Two Photon Absorption ◽  
Two Photon
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