Characterization of the micelle structure of oleic acid-based gemini surfactants: effect of stereochemistry

2018 ◽  
Vol 20 (13) ◽  
pp. 8874-8880 ◽  
Author(s):  
Tadashi Sugahara ◽  
Yuichiro Takamatsu ◽  
Avinash Bhadani ◽  
Masaaki Akamatsu ◽  
Kenichi Sakai ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Gemini Surfactant ◽  
Gemini Surfactants ◽  
Micelle Structure ◽  
Self Aggregation

In this study, we synthesize a novel oleic acid-based gemini surfactant with carboxylate headgroups, and study the effect of stereochemistry (anti- vs. syn-) on self-aggregation properties in water.

scholarly journals Small-angle Neutron Scattering Study of Micelle Structure and Hydration Behavior of Oleic Acid-based Gemini Surfactant

2019 ◽  
Vol 48 (9) ◽  
pp. 1050-1053 ◽  
Author(s):  
Tadashi Sugahara ◽  
Masaaki Akamatsu ◽  
Hiroki Iwase ◽  
Yuichiro Takamatsu ◽  
Kenichi Sakai ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Gemini Surfactant ◽  
Micelle Structure ◽  
Scattering Study ◽  
Neutron Scattering Study

Formulation and Characterization of Oleic Acid Magnetic PEG PLGA Nanoparticles for Targeting Glioblastoma Multiforme

2021 ◽  
pp. 167970
Author(s):  
Khushboo Jani ◽  
Neeraj Kaushal ◽  
Mostafa Sadoqi ◽  
Gen Long ◽  
Zhe-Sheng Chen ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Glioblastoma Multiforme ◽  
Plga Nanoparticles

scholarly journals Synthesis and Characterization of a Bioconjugate Based on Oleic Acid and L-Cysteine

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1791
Author(s):  
Marco Vizcarra-Pacheco ◽  
María Ley-Flores ◽  
Ana Mizrahim Matrecitos-Burruel ◽  
Ricardo López-Esparza ◽  
Daniel Fernández-Quiroz ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Materials Science ◽  
Critical Micellar Concentration ◽  
Synthesis And Characterization ◽  
New Materials ◽  
Visible Spectroscopy ◽  
Amide Bonds ◽  
Transmission Electron ◽  
Self Assembled

One of the main challenges facing materials science today is the synthesis of new biodegradable and biocompatible materials capable of improving existing ones. This work focused on the synthesis of new biomaterials from the bioconjugation of oleic acid with L-cysteine using carbodiimide. The resulting reaction leads to amide bonds between the carboxylic acid of oleic acid and the primary amine of L-cysteine. The formation of the bioconjugate was corroborated by Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, and nuclear magnetic resonance (NMR). In these techniques, the development of new materials with marked differences with the precursors was confirmed. Furthermore, NMR has elucidated a surfactant structure, with a hydrophilic part and a hydrophobic section. Ultraviolet-visible spectroscopy (UV-Vis) was used to determine the critical micellar concentration (CMC) of the bioconjugate. Subsequently, light diffraction (DLS) was used to analyze the size of the resulting self-assembled structures. Finally, transmission electron microscopy (TEM) was obtained, where the shape and size of the self-assembled structures were appreciated.

scholarly journals Synthesis and Characterization of Partially Renewable Oleic Acid-Based Ionomers for Proton Exchange Membranes

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 130
Author(s):  
Carlos Corona-García ◽  
Alejandro Onchi ◽  
Arlette A. Santiago ◽  
Araceli Martínez ◽  
Daniella Esperanza Pacheco-Catalán ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Proton Conductivity ◽  
Electrochemical Impedance ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Molar Ratio ◽  
Aromatic Diamines ◽  
Chemical Structures ◽  
Long Chain

The future availability of synthetic polymers is compromised due to the continuous depletion of fossil reserves; thus, the quest for sustainable and eco-friendly specialty polymers is of the utmost importance to ensure our lifestyle. In this regard, this study reports on the use of oleic acid as a renewable source to develop new ionomers intended for proton exchange membranes. Firstly, the cross-metathesis of oleic acid was conducted to yield a renewable and unsaturated long-chain aliphatic dicarboxylic acid, which was further subjected to polycondensation reactions with two aromatic diamines, 4,4′-(hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline and 4,4′-diamino-2,2′-stilbenedisulfonic acid, as comonomers for the synthesis of a series of partially renewable aromatic-aliphatic polyamides with an increasing degree of sulfonation (DS). The polymer chemical structures were confirmed by Fourier transform infrared (FTIR) and nuclear magnetic resonance (1H, 13C, and 19F NMR) spectroscopy, which revealed that the DS was effectively tailored by adjusting the feed molar ratio of the diamines. Next, we performed a study involving the ion exchange capacity, the water uptake, and the proton conductivity in membranes prepared from these partially renewable long-chain polyamides, along with a thorough characterization of the thermomechanical and physical properties. The highest value of the proton conductivity determined by electrochemical impedance spectroscopy (EIS) was found to be 1.55 mS cm−1 at 30 °C after activation of the polymer membrane.

Self-aggregation properties of new ester-based gemini surfactants and their rheological behavior in the presence of cosurfactant — monolaurin

2014 ◽  
Vol 461 ◽  
pp. 258-266 ◽  
Author(s):  
Avinash Bhadani ◽  
Rekha Goswami Shrestha ◽  
Setsuko Koura ◽  
Takeshi Endo ◽  
Kenichi Sakai ◽  
...  
Keyword(s):  
Rheological Behavior ◽  
Gemini Surfactants ◽  
Self Aggregation

Surface Activity Research of Cationic Gemini Surfactants

2013 ◽  
Vol 690-693 ◽  
pp. 2076-2080
Author(s):  
Zhen Zhong Fan ◽  
Lan Lan Li ◽  
Li Feng Zhang ◽  
Qing Wang Liu
Keyword(s):  
Surface Tension ◽  
Critical Micelle Concentration ◽  
Surface Activity ◽  
Surfactant Concentration ◽  
Gemini Surfactant ◽  
Gemini Surfactants ◽  
Ph Value ◽  
Inorganic Salts ◽  
Cationic Gemini Surfactant ◽  
Cationic Gemini Surfactants

Cationic Gemini surfactant concentration, the inorganic salts added and the pH value of surface tension obtained cationic gemini surfactant critical micelle concentration is 0.4mmol / L;by adding three kinds of inorganic salts NaCl, MgCl2, and Na2SO4 ,which Na2SO4 has the greatest impact on surface tension, followed by MgCl2.The surface minimum tension of the pH ranged from 9 to 11 , indicating that the surface activity of cationic gemini surfactants achieved the highest.

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