Preparation, optimization and evolution of the kinetic mechanism of an Fe-MIL-88A metal–organic framework

CrystEngComm ◽  
2019 ◽  
Vol 21 (3) ◽  
pp. 544-553 ◽  
Author(s):  
Elham Bagherzadeh ◽  
Seyed Mojtaba Zebarjad ◽  
Hamid Reza Madaah Hosseini ◽  
Pierre Chagnon
Keyword(s):  
Morphological Changes ◽  
Metal Organic Framework ◽  
Kinetic Mechanism ◽  
Nucleation Mechanism ◽  
Growth Behavior ◽  
Kinetics Of Crystallization ◽  
Metal Organic ◽  
Statistical Studies ◽  
Kinetics Of ◽  
Organic Framework

Investigating the kinetics of crystallization, growth behavior and morphological changes through statistical studies of Fe-MIL-88A suggested an autocatalytic nucleation mechanism.

scholarly journals Kinetics of cooperative CO2 adsorption in diamine-appended variants of the metal–organic framework Mg2(dobpdc)

2020 ◽  
Vol 11 (25) ◽  
pp. 6457-6471 ◽  
Author(s):  
Jeffrey D. Martell ◽  
Phillip J. Milner ◽  
Rebecca L. Siegelman ◽  
Jeffrey R. Long
Keyword(s):  
Adsorption Kinetics ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Performance Properties ◽  
Metal Organic ◽  
Kinetics Of ◽  
Insight Into ◽  
Organic Framework

An in-depth investigation of the CO2 adsorption kinetics of a promising class of cooperative carbon capture materials offers new insight into their structure-performance properties.

scholarly journals An exceptionally stable octacobalt-cluster-based metal–organic framework for enhanced water oxidation catalysis

2019 ◽  
Vol 10 (42) ◽  
pp. 9859-9864 ◽  
Author(s):  
Ning-Yu Huang ◽  
Jian-Qiang Shen ◽  
Zi-Ming Ye ◽  
Wei-Xiong Zhang ◽  
Pei-Qin Liao ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Adsorption Energy ◽  
Water Oxidation ◽  
Metal Organic Framework ◽  
Oxidation Catalysis ◽  
Cobalt Ions ◽  
Water Oxidation Catalysis ◽  
Metal Organic ◽  
Kinetics Of ◽  
Organic Framework

The site, capping four coplanar cobalt ions, has a near-optimal OH− adsorption energy, which is beneficial to accelerate the reaction kinetics of water oxidation catalysis.

Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

2012 ◽  
Vol 41 (40) ◽  
pp. 12346 ◽  
Author(s):  
Anuradha Roy ◽  
Avanish K. Srivastava ◽  
Beer Singh ◽  
Dilip Shah ◽  
Timir Haran Mahato ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Kinetics Of Degradation ◽  
Kinetics Of ◽  
Organic Framework

Metal–organic framework derived yolk–shell NiS2/carbon spheres for lithium–sulfur batteries with enhanced polysulfide redox kinetics

2019 ◽  
Vol 55 (22) ◽  
pp. 3243-3246 ◽  
Author(s):  
Yaxi Tian ◽  
Huawen Huang ◽  
Guoxue Liu ◽  
Ran Bi ◽  
Lei Zhang
Keyword(s):  
Shell Structure ◽  
Metal Organic Framework ◽  
Electrochemical Performances ◽  
Carbon Spheres ◽  
Redox Kinetics ◽  
Lithium Sulfur Batteries ◽  
Metal Organic ◽  
Kinetics Of ◽  
Lithium Sulfur ◽  
Organic Framework

A yolk–shell NiS2/C–S cathode exhibits enhanced electrochemical performances in lithium–sulfur batteries due to the improved redox kinetics of polysulfide confined within the yolk–shell structure.

Metallic Ni nanocatalyst in situ formed from a metal–organic-framework by mechanochemical reaction for hydrogen storage in magnesium

2015 ◽  
Vol 3 (16) ◽  
pp. 8294-8299 ◽  
Author(s):  
Yi Jia ◽  
Chenghua Sun ◽  
Ye Peng ◽  
Wenqi Fang ◽  
Xuecheng Yan ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Metal Organic Framework ◽  
Mechanochemical Reaction ◽  
Hydrogen Storage Materials ◽  
Storage Materials ◽  
Metal Organic ◽  
Kinetics Of ◽  
Organic Framework

The facile and scalable fabrication of ultrafine (<5 nm) nanoparticles (NPs) as effective catalysts is the key for enhancing the kinetics of most hydrogen storage materials (HSMs).

Accelerated Formation Kinetics of a Multicomponent Metal–Organic Framework Derived from Preferential Site Occupancy

2020 ◽  
Vol 59 (13) ◽  
pp. 9350-9355
Author(s):  
Shing Bo Peh ◽  
Shibo Xi ◽  
Avishek Karmakar ◽  
Jing Ying Yeo ◽  
Yuxiang Wang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Site Occupancy ◽  
Formation Kinetics ◽  
Preferential Site ◽  
Metal Organic ◽  
Kinetics Of ◽  
Organic Framework
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