More versatility than thought: large {Zr26} oxocarboxylate cluster by corner-sharing of standard octahedral subunits

CrystEngComm ◽  
2018 ◽  
Vol 20 (35) ◽  
pp. 5132-5136 ◽  
Author(s):  
Bahareh Nateghi ◽  
Ishtvan Boldog ◽  
Konstiantyn V. Domasevitch ◽  
Christoph Janiak
Keyword(s):  
Zirconium Cluster

The largest known zirconium cluster with an idealized formula of [Zr26O18(OH)30(HCOO)38] was obtained via solvolysis of ZrOCl2 in DMF/HCOOH.

Two families of centered zirconium cluster phases with M1,2M'Cl6.Zr6Cl12Z compositions

1993 ◽  
Vol 32 (9) ◽  
pp. 1566-1572 ◽  
Author(s):  
Jie Zhang ◽  
John D. Corbett
Keyword(s):  
Zirconium Cluster

Encapsulation of the transition metals chromium through cobalt in zirconium cluster iodides

1988 ◽  
Vol 110 (5) ◽  
pp. 1511-1516 ◽  
Author(s):  
Timothy. Hughbanks ◽  
Guy. Rosenthal ◽  
John D. Corbett
Keyword(s):  
Transition Metals ◽  
Zirconium Cluster

Synthesis and Structure of and Cation Distribution in the Zirconium Cluster Rb[(Zr6C)Cl15]

2008 ◽  
Vol 63 (5) ◽  
pp. 507-512 ◽  
Author(s):  
Henning W. Rohm ◽  
Martin Köckerling
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Cation Distribution ◽  
Type Structure ◽  
The Other ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coulombic Interactions ◽  
Cluster Network ◽  
Zirconium Cluster

Rb[(Zr6C)Cl15] was prepared by heating ZrCl4, Zr powder, RbCl and Al4C3 at 850 °C for 21 days. The crystal structure was determined by single crystal X-ray diffraction (space group Pmma, a = 18.484(3), b = 18.962(2), c = 9.708(1) Å, V = 2505.4(6) Å3, and Z = 4). Rb[(Zr6C)Cl15] crystallises in the Cs[Nb6Cl15]-type structure. It is built up from two interconnected types of cluster chains, one with linear Zr−Cla−a-Zr bridges, the other one with bent bridges. The rubidium cations are spread over three different sites within the cluster network which differs significantly from the cation distribution in the comparable potassium and caesium phases. The cation distribution can be rationalised considering the size of the cavities and the Coulombic interactions.

scholarly journals Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs

2019 ◽  
Vol 386 ◽  
pp. 32-49 ◽  
Author(s):  
Zhijie Chen ◽  
Sylvia L. Hanna ◽  
Louis R. Redfern ◽  
Dalal Alezi ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Zirconium Cluster

New Complexes of Zirconium(IV) and Hafnium(IV) with Heteroscorpionate Ligands and the Hydrolysis of Such Complexes To Give a Zirconium Cluster#

2004 ◽  
Vol 43 (4) ◽  
pp. 1350-1358 ◽  
Author(s):  
A. Otero ◽  
J. Fernández-Baeza ◽  
A. Antiñolo ◽  
J. Tejeda ◽  
A. Lara-Sánchez ◽  
...  
Keyword(s):  
Zirconium Cluster ◽  
Hydrolysis Of

Preparation and structure of a reduced-state zirconium cluster containing triangular [Zr3Cl6]n+ units

1980 ◽  
Vol 19 (10) ◽  
pp. 3172-3175 ◽  
Author(s):  
James Kleppinger ◽  
Julie Wrazel ◽  
Joseph C. Calabrese ◽  
Edwin M. Larsen
Keyword(s):  
Zirconium Cluster ◽  
Reduced State
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