scholarly journals Efficient extraction of inorganic selenium from water by a Zr metal–organic framework: investigation of volumetric uptake capacity and binding motifs

CrystEngComm ◽  
2018 ◽  
Vol 20 (40) ◽  
pp. 6140-6145 ◽  
Author(s):  
Riki J. Drout ◽  
Ashlee J. Howarth ◽  
Ken-ichi Otake ◽  
Timur Islamoglu ◽  
Omar K. Farha
Keyword(s):  
Metal Organic Framework ◽  
Uptake Capacity ◽  
Binding Motifs ◽  
Inorganic Selenium ◽  
Metal Organic ◽  
Efficient Extraction ◽  
Organic Framework

MOF-808 displays enhanced gravimetric and volumetric uptake capacities for selenium oxyanions and the binding motifs are crystallographically characterized.

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

A zinc(ii) metal–organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid

CrystEngComm ◽  
2019 ◽  
Vol 21 (24) ◽  
pp. 3679-3685 ◽  
Author(s):  
Donghai Sheng ◽  
Ying Zhang ◽  
Yang Han ◽  
Guang Xu ◽  
Qingxiang Song ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Uptake Capacity ◽  
High Affinity ◽  
Metal Organic ◽  
Organic Framework

A new metal–organic framework {[Zn2(Htzba)2(dmtrz)]·(CH3)2NH}n (1) has already been solvothermally synthesized that exhibits a high CO2 uptake capacity.

Ultrafast and Efficient Extraction of Uranium from Seawater Using an Amidoxime Appended Metal–Organic Framework

2017 ◽  
Vol 9 (38) ◽  
pp. 32446-32451 ◽  
Author(s):  
Long Chen ◽  
Zhuanling Bai ◽  
Lin Zhu ◽  
Linjuan Zhang ◽  
Yawen Cai ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic ◽  
Efficient Extraction ◽  
Uranium From Seawater ◽  
Organic Framework

A highly porous 4,4-paddlewheel-connected NbO-type metal–organic framework with a large gas-uptake capacity

2013 ◽  
Vol 42 (31) ◽  
pp. 11304 ◽  
Author(s):  
Zhaoxu Wang ◽  
Baishu Zheng ◽  
Heting Liu ◽  
Pinggui Yi ◽  
Xiaofang Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Uptake Capacity ◽  
Gas Uptake ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A new Co-nitroimidazolate–dicarboxylate pillared-layer network with various types of channels and ultra-large cages for gas uptake

CrystEngComm ◽  
2016 ◽  
Vol 18 (10) ◽  
pp. 1768-1774 ◽  
Author(s):  
Xiao-Qing Guo ◽  
Miao Wang ◽  
Yan-Feng Tang ◽  
Fei Meng ◽  
Guo-Qing Jiang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Uptake Capacity ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

A 3-D pillared-layer metal–organic framework constructed from unprecedented Co3-Co2-bdc-based layers and 2-nitroimidazole as pillars exhibits various types of pores and a nanometer-sized cavity along with a high CO2 uptake capacity (73.3 cm3 g−1 at 273 K and 1 atm).

Selective CO2 adsorption in a microporous metal–organic framework with suitable pore sizes and open metal sites

2015 ◽  
Vol 2 (6) ◽  
pp. 550-557 ◽  
Author(s):  
Bo Liu ◽  
Ya-Hui Jiang ◽  
Zhi-Sen Li ◽  
Lei Hou ◽  
Yao-Yu Wang
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Porous System ◽  
Uptake Capacity ◽  
Pore Sizes ◽  
Open Metal Sites ◽  
Metal Organic ◽  
High Polarity ◽  
Organic Framework

A new microporous framework was constructed from uncommon ternary SBUs with a rare (5,5,5)-connected topology, which contains pores of suitable sizes and a high polarity porous system, exhibits a higher uptake capacity for CO2 and is highly selective for CO2 over N2 and CH4 gases.

Functionalized metal–organic framework as a new platform for efficient and selective removal of cadmium(ii) from aqueous solution

2015 ◽  
Vol 3 (29) ◽  
pp. 15292-15298 ◽  
Author(s):  
Yang Wang ◽  
Guiqin Ye ◽  
Huanhuan Chen ◽  
Xiaoya Hu ◽  
Zheng Niu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Sulfonic Acid ◽  
Metal Organic Framework ◽  
Selective Removal ◽  
Cadmium Uptake ◽  
Uptake Capacity ◽  
Fast Kinetics ◽  
Cadmium Ions ◽  
Metal Organic ◽  
Organic Framework

The MOF, Cu3(BTC)2 functionalized with sulfonic acid via sequential post-synthetic modification and oxidation demonstrates high cadmium uptake capacity and fast kinetics for adsorbing cadmium ions from aqueous solution.

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