V-modified Co3O4nanorods with superior catalytic activity and thermostability for CO oxidation

CrystEngComm ◽  
2018 ◽  
Vol 20 (35) ◽  
pp. 5191-5199 ◽  
Author(s):  
Kun Wang ◽  
Baolin Liu ◽  
Yali Cao ◽  
Yizhao Li ◽  
Dianzeng Jia

Solid-state chemical strategy was applied to synthesize V-modified Co3O4nanorods with high catalytic activity and thermostability for CO oxidation.

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 131 ◽  
Author(s):  
Rola Mohammad Al Soubaihi ◽  
Khaled Mohammad Saoud ◽  
Myo Tay Zar Myint ◽  
Mats A. Göthelid ◽  
Joydeep Dutta

Carbon monoxide (CO) oxidation is considered an important reaction in heterogeneous industrial catalysis and has been extensively studied. Pd supported on SiO2 aerogel catalysts exhibit good catalytic activity toward this reaction owing to their CO bond activation capability and thermal stability. Pd/SiO2 catalysts were investigated using carbon monoxide (CO) oxidation as a model reaction. The catalyst becomes active, and the conversion increases after the temperature reaches the ignition temperature (Tig). A normal hysteresis in carbon monoxide (CO) oxidation has been observed, where the catalysts continue to exhibit high catalytic activity (CO conversion remains at 100%) during the extinction even at temperatures lower than Tig. The catalyst was characterized using BET, TEM, XPS, TGA-DSC, and FTIR. In this work, the influence of pretreatment conditions and stability of the active sites on the catalytic activity and hysteresis is presented. The CO oxidation on the Pd/SiO2 catalyst has been attributed to the dissociative adsorption of molecular oxygen and the activation of the C-O bond, followed by diffusion of adsorbates at Tig to form CO2. Whereas, the hysteresis has been explained by the enhanced stability of the active site caused by thermal effects, pretreatment conditions, Pd-SiO2 support interaction, and PdO formation and decomposition.


2011 ◽  
Vol 133 (10) ◽  
pp. 3444-3451 ◽  
Author(s):  
Fan Yang ◽  
Jesús Graciani ◽  
Jaime Evans ◽  
Ping Liu ◽  
Jan Hrbek ◽  
...  

2019 ◽  
Vol 777 ◽  
pp. 655-662 ◽  
Author(s):  
A.V. Egorysheva ◽  
O.G. Ellert ◽  
E. Yu Liberman ◽  
D.I. Kirdyankin ◽  
S.V. Golodukhina ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93985-93996 ◽  
Author(s):  
Yanan Tang ◽  
Jincheng Zhou ◽  
Zigang Shen ◽  
Weiguang Chen ◽  
Chenggang Li ◽  
...  

The geometric, electronic and catalytic characters of Fe atom embedded graphene (including monovacancy and divacancy) are investigated using the first-principles method, which gives a reference on designing graphene-based catalysts for CO oxidation.


2020 ◽  
Vol 56 (88) ◽  
pp. 13615-13618 ◽  
Author(s):  
Na Pan ◽  
Hanwen Zhang ◽  
Bo Yang ◽  
Hui Qiu ◽  
Longyan Li ◽  
...  

A new class of conductive MOFs can be directly used as a bifunctional electrocatalyst for both the ORR and OER. By adding Ru into the pristine MOF, the resultant catalyst exhibits high catalytic activity in all-solid-state Zn–air batteries.


2020 ◽  
Vol 2 (11) ◽  
pp. 5384-5395
Author(s):  
Dinabandhu Patra ◽  
Srinivasa Rao Nalluri ◽  
Hui Ru Tan ◽  
Mohammad S. M. Saifullah ◽  
Ramakrishnan Ganesan ◽  
...  

Active sites are preserved in the citric acid-capped Au nanoclusters prepared in solid state. In water, the rapid dissolution of citric acid allows the reactants to easily access the active sites of infant Au nanoclusters leading to faster catalysis.


2015 ◽  
Vol 51 (87) ◽  
pp. 15823-15826 ◽  
Author(s):  
Junya Ohyama ◽  
Taiki Koketsu ◽  
Yuta Yamamoto ◽  
Shigeo Arai ◽  
Atsushi Satsuma

Au/TiO2 prepared by CO treatment showed high catalytic activity for CO oxidation due to twinned structure of Au nanoparticles.


2015 ◽  
Vol 39 (3) ◽  
pp. 1742-1748 ◽  
Author(s):  
Gengnan Li ◽  
Liang Li ◽  
Yongsheng Li ◽  
Jianlin Shi

Compared with pure Co3O4 spinel, the Fe-doped catalyst demonstrates high catalytic activity and stability in low temperature CO oxidation under moisture conditions.


2012 ◽  
Vol 296 ◽  
pp. 110-119 ◽  
Author(s):  
Hai-Feng Wang ◽  
Richard Kavanagh ◽  
Yang-Long Guo ◽  
Yun Guo ◽  
Guanzhong Lu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document