Optimizing crystallinity and porosity of hierarchical Ni(OH)2 through conformal transformation of metal–organic framework template for supercapacitor applications

CrystEngComm ◽  
2018 ◽  
Vol 20 (30) ◽  
pp. 4313-4320 ◽  
Author(s):  
Haobing Zhang ◽  
Ben Xu ◽  
Zhenyu Xiao ◽  
Hao Mei ◽  
Liangliang Zhang ◽  
...  
Keyword(s):  
Conformal Transformation ◽  
High Performance ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Hydrolysis Of ◽  
Supercapacitor Applications ◽  
Organic Framework

Conformal hydrolysis of MOFs (metal–organic frameworks) yields high-performance supercapacitor electrodes.

“All-in-One” Hypergolic Metal-Organic Frameworks with High Energy Density and Short Ignition Delay

2022 ◽  
Author(s):  
Zhimin Li ◽  
Yi-Qiang Xu ◽  
Chao Wang ◽  
Guorong Lei ◽  
Rui Zhang ◽  
...  
Keyword(s):  
Energy Density ◽  
Ignition Delay ◽  
High Performance ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
High Energy ◽  
High Energy Density ◽  
Vital Importance ◽  
Metal Organic ◽  
Organic Framework

Constructing high performance hypergolic propellant is of vital importance yet challenging. Herein, by taking metal organic framework(MOF) as a propotypical system, we proposed that co-assembled functional cyanotetrazolylborohydride (CTB) and imidazole...

Tri-functional Fe–Zr bi-metal–organic frameworks enable high-performance phosphate ion ratiometric fluorescent detection

Nanoscale ◽  
2020 ◽  
Vol 12 (37) ◽  
pp. 19383-19389
Author(s):  
Xin Li ◽  
Peng Liu ◽  
Xiangheng Niu ◽  
Kun Ye ◽  
Liang Ni ◽  
...  
Keyword(s):  
High Performance ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Intrinsic Fluorescence ◽  
Fluorescent Detection ◽  
Specific Recognition ◽  
Phosphate Ion ◽  
Ion Sensing ◽  
Metal Organic ◽  
Organic Framework

A Fe–Zr bi-metal–organic framework with three functions (intrinsic fluorescence, peroxidase-mimicking activity, and specific recognition) is designed to establish a ratiometric fluorescent platform for high-performance phosphate ion sensing.

Bimetallic metal–organic framework derived porous carbon nanostructures for high performance membrane capacitive desalination

2017 ◽  
Vol 5 (13) ◽  
pp. 6113-6121 ◽  
Author(s):  
Meng Ding ◽  
Wenhui Shi ◽  
Lu Guo ◽  
Zhi Yi Leong ◽  
Avinash Baji ◽  
...  
Keyword(s):  
Metal Ions ◽  
Porous Carbon ◽  
Carbon Nanostructures ◽  
High Performance ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Porous Carbons ◽  
Optimal Ratio ◽  
Metal Organic ◽  
Organic Framework

Porous carbons derived from bimetallic metal–organic frameworks exhibit tunable properties by controlling the ratio of metal ions (Zn and Co) in the precursors. With the optimal ratio of Zn/Co = 3 in the precursors, the porous carbons possess a superior electrosorption capacity of 45.6 mg g−1.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma
Keyword(s):  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Flexible Structures ◽  
Biodiesel Production ◽  
Biodiesel Synthesis ◽  
Metal Organic ◽  
Organic Framework

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

A binuclear Co-based metal-organic framework towards efficient oxygen evolution reaction

2021 ◽  
Author(s):  
Ning Liu ◽  
Qiaoqiao Zhang ◽  
Jingqi Guan
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Research Interest ◽  
Metal Organic ◽  
Organic Framework

Seeking for low-cost and high-performance electrocatalysts for oxygen evolution reaction (OER) has drawn enormous research interest in the last few years. Reported herein is the topotactic construction of a binuclear...

scholarly journals Crystal growth of the core and rotated epitaxial shell of a heterometallic metal-organic framework revealed with atomic force microscopy

2021 ◽  
Author(s):  
Fajar Inggit Pambudi ◽  
Michael William Anderson ◽  
Martin Attfield
Keyword(s):  
Atomic Force Microscopy ◽  
Crystal Growth ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Force Microscopy ◽  
The Core ◽  
Atomic Force ◽  
Metal Organic ◽  
Surface Crystal ◽  
Organic Framework

Atomic force microscopy has been used to determine the surface crystal growth of two isostructural metal-organic frameworks, [Zn2(ndc)2(dabco)] (ndc = 1,4-naphthalene dicarboxylate, dabco = 4-diazabicyclo[2.2.2]octane) (1) and [Cu2(ndc)2(dabco)] (2) from...

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