Lone pair–π vs. σ-hole–π interactions in bromine head-containing oxacalix[2]arene[2]triazines

CrystEngComm ◽  
2018 ◽  
Vol 20 (23) ◽  
pp. 3251-3257 ◽  
Author(s):  
Muhammad Moazzam Naseer ◽  
Antonio Bauzá ◽  
Hazem Alnasr ◽  
Klaus Jurkschat ◽  
Antonio Frontera
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Lone Pair ◽  
State Structure ◽  
Solid State Structure ◽  
Π Interactions ◽  
Supramolecular Chain

New bromine head-containing oxacalix[2]arene[2]triazines were synthesized. Owing to the bromine head and complementary V-shaped cavity, the solid state structure showed an intriguing and unique 1D-supramolecular chain-like self-assembly.

Halogen bonding and π–π interactions in the solid-state structure of a butadiynylene-linked bis(iodoperfluoroarene)

CrystEngComm ◽  
2013 ◽  
Vol 15 (16) ◽  
pp. 3097 ◽  
Author(s):  
Sebastian M. Walter ◽  
Mohammed G. Sarwar ◽  
Michael G. Chudzinski ◽  
Eberhardt Herdtweck ◽  
Alan J. Lough ◽  
...  
Keyword(s):  
Solid State ◽  
Halogen Bonding ◽  
State Structure ◽  
Solid State Structure ◽  
Π Interactions

scholarly journals Synthesis, solid state self-assembly driven by antiparallel π⋯π stacking and {⋯H–C–C–F}2 dimer synthons, and in vitro acetyl cholinesterase inhibition activity of phenoxy pendant isatins

RSC Advances ◽  
2022 ◽  
Vol 12 (3) ◽  
pp. 1788-1796
Author(s):  
Saba Mehreen ◽  
Aman Ullah ◽  
Humaira Nadeem ◽  
Necmi Dege ◽  
Muhammad Moazzam Naseer
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Cholinesterase Inhibition ◽  
Inhibition Activity ◽  
State Structure ◽  
Acetyl Cholinesterase ◽  
Solid State Structure ◽  
Π Stacking ◽  
Self Assembled

The phenoxy pendant isatins were observed to be highly potent inhibitors of acetylcholinesterase. In addition, the solid-state structure of a phenoxy pendant isatin showed an intriguing 1D-supramolecular self-assembled structure.

Synthesis and solid state structure for a series of poly(1-pyrrolylmethyl)benzene derivatives. Control of the interplaying π–π and C–H⋯π interactions?

CrystEngComm ◽  
2006 ◽  
Author(s):  
José Giner Planas ◽  
Carles Masalles ◽  
Reijo Sillanpää ◽  
Raikko Kivekäs ◽  
Francesc Teixidor ◽  
...  
Keyword(s):  
Solid State ◽  
Benzene Derivatives ◽  
State Structure ◽  
Solid State Structure ◽  
Π Interactions

Synthesis and Solid-State Structure of Tetrabutylammonium Imidazolate-Dipyrrole Formed by Self Assembly

2009 ◽  
Vol 2009 (11) ◽  
pp. 1687-1690 ◽  
Author(s):  
Manfred T. Reetz ◽  
H. Martin Herzog ◽  
Richard Goddard
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
State Structure ◽  
Solid State Structure

scholarly journals 2,5-Dimethylbufotenine and 2,5-dimethylbufotenidine: novel derivatives of natural tryptamines found in Bufo alvarius toads

2021 ◽  
Vol 77 (2) ◽  
pp. 190-194
Author(s):  
Duyen N. K. Pham ◽  
Andrew R. Chadeayne ◽  
James A. Golen ◽  
David R. Manke
Keyword(s):  
Solid State ◽  
Hydrogen Bonds ◽  
Water Molecule ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
State Structure ◽  
Solid State Structure ◽  
Π Interactions ◽  
Iodide Anion ◽  
Derivatives Of

The solid-state structure of the bufotenine derivative bis(5-methoxy-2,N,N-trimethyltryptammonium) (5-MeO-2-Me-DMT) fumarate (systematic name: bis{[2-(5-methoxy-2-methyl-1H-indol-3-yl)ethyl]dimethylazanium} (2E)-but-2-enedioate), 2C14H21N2O+·C4H2O4 2−, the bufotenidine derivative 5-methoxy-2,N,N,N-tetramethyltryptammonium (5-MeO-2-Me-TMT) iodide {systematic name: [2-(5-methoxy-2-methyl-1H-indol-3-yl)ethyl]trimethylazanium iodide}, C15H23N2O+·I−, and the hydrate of the same {systematic name: [2-(5-methoxy-2-methyl-1H-indol-3-yl)ethyl]trimethylazanium iodide monohydrate}, C15H23N2O+·I−·H2O, are reported. The structure of 5-MeO-2-Me-DMT fumarate possesses one tryptammonium cation and a half of a fumarate dianion in the asymmetric unit, linked together by N—H...O hydrogen bonds in infinite two-dimensional networks parallel to the (101) plane. The structure of 5-MeO-2-Me-TMT iodide possesses one tryptammonium cation and one iodide anion in the asymmetric unit. The ions are linked via N—H...I hydrogen bonds, and indoles are coupled in dimers through π–π interactions. The hydrate of 5-MeO-2-Me-TMT iodide possesses one tryptammonium cation, one iodide anion and one water molecule in the asymmetric unit. It shows N—H...I and O—H...I hydrogen bonds that couple the tryptammonium cations into dimers.

scholarly journals Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π–π stacking interactions

2018 ◽  
Vol 33 (2) ◽  
pp. 13
Author(s):  
X. H. Li ◽  
A. F. Jalbout ◽  
W. D. Xiang
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Weak Interactions ◽  
State Structure ◽  
X Ray Diffraction ◽  
Solid State Structure ◽  
X Ray ◽  
Supramolecular Architectures ◽  
Π Stacking ◽  
Π Stacking Interaction

A new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure.

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