Nanotube-shaped PtFe intermetallics: controlled synthesis, crystal structure, and improved electrocatalytic activities

CrystEngComm ◽  
2018 ◽  
Vol 20 (30) ◽  
pp. 4277-4282 ◽  
Author(s):  
Xuebin Zhang ◽  
Shujun Tian ◽  
Wenjing Yu ◽  
Bingqing Lu ◽  
Tianyang Shen ◽  
...  

Nanotube-shaped PtFe intermetallics synthesized over charged β-FeOOH by self-assembly and careful heat treatment exhibit higher Pt activities toward methanol electro-oxidation.

Author(s):  
Alireza Kavand ◽  
Christophe A. Serra ◽  
Christian Blanck ◽  
Marc Lenertz ◽  
Nicolas Anton ◽  
...  

2010 ◽  
Vol 114 (14) ◽  
pp. 4802-4810 ◽  
Author(s):  
Xiangkui Ren ◽  
Bin Sun ◽  
Chi-Chun Tsai ◽  
Yingfeng Tu ◽  
Siwei Leng ◽  
...  

2015 ◽  
Vol 1784 ◽  
Author(s):  
Mingu Kim ◽  
Gwanghyo Choi ◽  
Daeheung Yoo ◽  
Kwangmin Lee

ABSTRACTThe band gap energy of the TiO2 photocatalytic is high at 3.2 eV. Ultraviolet (UV) light irradiation (<388nm) is required for the photocatalytic application. The lowering the band gap energy of TiO2 and enlarging light absorbing area are effective ways to enhance the efficiency of photocatalytic activity. Furthermore, the morphology and crystal structure of nanosized TiO2 considerably influences its photocatalytic behavior.In this study, sodium titanate nanorods were formed using an alkali-treatment and were heat treated at different temperatures. The photoelectrochemical properties of sodium titanate nanorods was measured as a function of heat treatment temperature. The nanorods were prepared on the surface of Ti disk with a diameter of 15mm and a thickness of 3mm. Ti disk was immersed in 5 M NaOH aqueous solution at a temperature of 60 °C for 24 h. Morphology of sodium titanate nanorods was observed using FE-SEM. Crystal structure of sodium titanate nanorods was analyzed using X-ray diffractometer. Photoluminescence (PL) and electrochemical impedance spectroscopy (EIS) was used to evaluate photoelectrochemical properties of sodium titanate nanorods. The thin amorphous sodium titanate layer was formed during alkali-treatment. The sodium titanate layer was changed to nanorods after heat treatment at a temperature of 700 °C. The thickness and length of sodium titanate nanorods obtained at 700 °C were around 100 nm and 1μm, respectively. The crystal structure of sodium titanate was identified with Na2Ti6O13. Above 900 °C, the morphology of nanorods changed to agglomerated shape and the thickness of nanorods increased to 1 μm. The lowest value of PL was obtained at a temperature of 700 °C, while nonalkali treated specimen showed the highest value of PL. EIS revealed that polarization resistance at interface between sodium titanate nanorods and electrolyte was increased with increasing heat treatment temperature.


Minerals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 311 ◽  
Author(s):  
Carlotta Giacobbe ◽  
Jonathan Wright ◽  
Dario Di Giuseppe ◽  
Alessandro Zoboli ◽  
Mauro Zapparoli ◽  
...  

Nowadays, due to the adverse health effects associated with exposure to asbestos, its removal and thermal inertization has become one of the most promising ways for reducing waste risk management. Despite all the advances in structure analysis of fibers and characterization, some problems still remain that are very hard to solve. One challenge is the structure analysis of natural micro- and nano-crystalline samples, which do not form crystals large enough for single-crystal X-ray diffraction (SC-XRD), and their analysis is often hampered by reflection overlap and the coexistence of multiple fibres linked together. In this paper, we have used nano-focused synchrotron X-rays to refine the crystal structure of a micrometric tremolite fibres from Val d’Ala, Turin (Italy) after various heat treatment. The structure of the original fibre and after heating to 800 °C show minor differences, while the fibre that was heated at 1000 °C is recrystallized into pyroxene phases and cristobalite.


2015 ◽  
Vol 17 (41) ◽  
pp. 27653-27657 ◽  
Author(s):  
Jeffrey E. Chen ◽  
Hong-Yuan Lian ◽  
Saikat Dutta ◽  
Saad M. Alshehri ◽  
Yusuke Yamauchi ◽  
...  

This study illustrates the directed self-assembly of mesoporous TiO2 with magnetic properties due to its colloidal crystal structure with Fe3O4.


2009 ◽  
Vol 65 (a1) ◽  
pp. s90-s90
Author(s):  
Kinga Suwinska ◽  
Barbara Lesniewska ◽  
Said Jebors ◽  
Anthony W. Coleman

Author(s):  
Patricia Jovičević-Klug ◽  
Bojan Podgornik

Deep cryogenic treatment (DCT) is a type of cryogenic treatment, where a metallic material is subjected to temperatures below -150&deg;C, normally to temperatures of liquid nitrogen (-196 &deg;C). When a material is exposed to DCT as a part of heat treatment, changes in microstructure are induced due to new grain formation, changes in grain size, change in the solubility of atoms, movement of dislocations, alteration of crystal structure, and finally new phase formation. The metallic material's performance and later performance of manufactured components and tools from this specific material are dependent on the selection of proper design, proper material, accuracy with which the tool is made and application of proper heat treatment, including any eventual DCT. Metallic materials are ferrous and non-ferrous metals. In the last years ferrous metals (different grades of steel) and non-ferrous alloys (aluminum, magnesium, titanium, nickel etc.) have been increasingly treated with DCT to alter their properties. DCT treatment has shown to reduce density of defects in crystal structure, increase wear resistance of material, increase hardness, improve toughness, and reduce tensile strength and corrosion resistance. However, some researchers also reported results showing no change in properties (toughness, hardness, corrosion resistance, etc.) or even deterioration when subjected to DCT treatment. This leads to a lack of consistency and reliability of the treatment process, which is needed for successful application in industry. This review provides a synopsis of DCT usage and resulting effects on treated materials used in automotive industry.


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