A water stable microporous metal–organic framework based on rod SBUs: synthesis, structure and adsorption properties

CrystEngComm ◽  
2018 ◽  
Vol 20 (15) ◽  
pp. 2169-2174 ◽  
Author(s):  
Jiaqi Yuan ◽  
Li Mu ◽  
Jiantang Li ◽  
Lirong Zhang ◽  
Guanghua Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Water ◽  
Adsorption Properties ◽  
Water Stability ◽  
Metal Organic ◽  
Organic Framework

A microporous metal–organic framework based on rod SBUs with high water stability and good selectivity for CO2 separation has been successfully synthesized.

scholarly journals Synthesis of a metal–organic framework by plasma in liquid to increase reduced metal ions and enhance water stability

RSC Advances ◽  
2021 ◽  
Vol 11 (37) ◽  
pp. 22756-22760
Author(s):  
Moriyuki Kanno ◽  
Takashi Kitao ◽  
Tsuyohito Ito ◽  
Kazuo Terashima
Keyword(s):  
Metal Ions ◽  
Metal Organic Framework ◽  
High Water ◽  
Water Stability ◽  
Metal Organic ◽  
Organic Framework ◽  
Plasma In Liquid

Plasma in liquid provides a method for the synthesis of HKUST-1 with increased reduced metal ions and high water stability.

Low-coverage adsorption properties of the metal–organic framework MIL-47 studied by pulse chromatography and Monte Carlo simulations

2009 ◽  
Vol 11 (18) ◽  
pp. 3515 ◽  
Author(s):  
Vincent Finsy ◽  
Sofia Calero ◽  
Elena García-Pérez ◽  
Patrick J. Merkling ◽  
Gill Vedts ◽  
...  
Keyword(s):  
Monte Carlo ◽  
Monte Carlo Simulations ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Low Coverage ◽  
Organic Framework

scholarly journals MIL-91(Ti), a small pore metal–organic framework which fulfils several criteria: an upscaled green synthesis, excellent water stability, high CO2 selectivity and fast CO2 transport

2016 ◽  
Vol 4 (4) ◽  
pp. 1383-1389 ◽  
Author(s):  
Virginie Benoit ◽  
Renjith S. Pillai ◽  
Angelica Orsi ◽  
Périne Normand ◽  
Hervé Jobic ◽  
...  
Keyword(s):  
Green Synthesis ◽  
Metal Organic Framework ◽  
Water Stability ◽  
High Co2 ◽  
Co2 Transport ◽  
Small Pore ◽  
Metal Organic ◽  
Co2 Selectivity ◽  
Organic Framework

MIL-91(Ti) is shown to be one of the very few MOFs of real interest for CO2 capture.

scholarly journals Enhanced Water Stability and Photoresponsivity in Metal-Organic Framework (MOF): A Potential Tool to Combat Drug-resistant Bacteria

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Saleh A. Ahmed ◽  
Damayanti Bagchi ◽  
Hanadi A. Katouah ◽  
Md. Nur Hasan ◽  
Hatem M. Altass ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Charge Transfer ◽  
Metal Organic Framework ◽  
Resistant Bacteria ◽  
Ros Generation ◽  
Water Stability ◽  
Equal Proportion ◽  
Electronic Band ◽  
Metal Organic ◽  
Organic Framework

AbstractIn this work, we have successfully synthesized a bimetallic (Zinc and Cobalt) Zeolitic Imidazolate Framework (Zn50Co50-ZIF), a class in a wider microporous Metal-Organic Framework (MOF) family. The synthesized nanostructures maintain both water stability like ZIF-8 (solely Zn containing) and charge transfer electronic band in the visible optical spectrum as ZIF-67 (solely Co containing). Crystal structure from XRD, high resolution transmission electron microscopy (HRTEM) followed by elemental mapping (EDAX) confirm structural stability and omnipresence of the metal atoms (Zn and Co) across the nanomaterial with equal proportion. Existence of charge transfer state consistent with ZIF67 and intact ultrafast excited state dynamics of the imidazolate moiety in both ZIF-8 and ZIF-67, is evidenced from steady state and time resolved optical spectroscopy. The thermal and aqueous stabilities of Zn50Co50-ZIF are found to be better than ZIF-67 but comparable to ZIF-8 as evidenced by solubility, scanning electron microscopy (SEM) and XRD studies of the material in water. We have evaluated the photoinduced ROS generation by the mixed ZIF employing dichloro-dihydro-fluorescein diacetate (DCFH-DA) assay. We have also explored the potentiality of the synthesized material for the alternate remediation of methicillin resistant Staphylococcus aureus (MRSA) infection through the photoinduced reactive oxygen species (ROS) generation and methylene blue (MB) degradation kinetics.

A novel interpenetrated anion-pillared porous material with high water tolerance afforded efficient C2H2/C2H4 separation

2019 ◽  
Vol 55 (34) ◽  
pp. 5001-5004 ◽  
Author(s):  
Lifeng Yang ◽  
Anye Jin ◽  
Lisha Ge ◽  
Xili Cui ◽  
Huabin Xing
Keyword(s):  
Porous Material ◽  
Metal Organic Framework ◽  
High Water ◽  
Separation Performance ◽  
Highly Efficient ◽  
Water Tolerance ◽  
Metal Organic ◽  
Organic Framework

A novel water stable interpenetrated anion-pillared metal-organic framework afforded highly efficient C2H2/C2H4 separation performance.

A 9-connected metal–organic framework with gas adsorption properties

2011 ◽  
Vol 21 (40) ◽  
pp. 15909 ◽  
Author(s):  
Guojian Ren ◽  
Shuxia Liu ◽  
Fengji Ma ◽  
Feng Wei ◽  
Qun Tang ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Organic Framework

A novel zinc(ii) metal–organic framework with a diamond-like structure: synthesis, study of thermal robustness and gas adsorption properties

2016 ◽  
Vol 45 (3) ◽  
pp. 1233-1242 ◽  
Author(s):  
Miroslav Almáši ◽  
Vladimír Zeleňák ◽  
Arnošt Zukal ◽  
Juraj Kuchár ◽  
Jiří Čejka
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Clapeyron Equation ◽  
Structure Synthesis ◽  
Metal Organic ◽  
Organic Framework

A novel 3D metal–organic framework with a diamond-like structure has been synthesised and structurally characterized. Adsorption of Ar, CO2, H2 and N2 has been studied. Heats of CO2 and H2 adsorption were calculated according to the Clausius–Clapeyron equation.

A Simple Approach to Enhance the Water Stability of a Metal-Organic Framework

2016 ◽  
Vol 23 (1) ◽  
pp. 42-46 ◽  
Author(s):  
Yung-Han Shih ◽  
Yu-Ching Kuo ◽  
Stephen Lirio ◽  
Kun-Yun Wang ◽  
Chia-Her Lin ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Simple Approach ◽  
Water Stability ◽  
Metal Organic ◽  
Organic Framework
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