scholarly journals Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation

2019 ◽  
Vol 55 (3) ◽  
pp. 318-321 ◽  
Author(s):  
Jamie L. Carden ◽  
Lukas J. Gierlichs ◽  
Duncan F. Wass ◽  
Duncan L. Browne ◽  
Rebecca L. Melen

The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates.

2008 ◽  
Vol 62 (15) ◽  
pp. 2343-2346 ◽  
Author(s):  
XiaoJuan Zhang ◽  
Wei Jiang ◽  
Dan Song ◽  
JianXun Liu ◽  
FengSheng Li

2020 ◽  
Vol 99 (1) ◽  
pp. 16-19
Author(s):  
Muhammad SAJID ◽  
Muhammad AYOUB ◽  
Yoshimitsu UEMURA ◽  
Suzana YUSUP ◽  
Bawadi B ABDULLAH ◽  
...  

2005 ◽  
Vol 09 (03) ◽  
pp. 163-169 ◽  
Author(s):  
Farzad Bahadoran ◽  
Solmaz Dialameh

Substituted iron and cobalt phthalocyanines are easily prepared by microwave irradiation of the starting materials under solvent free condition, which reduced reaction time considerably. The synthesized metallophthalocyanines (octachloro-, tetranitro-, tetracarboxy- or polyphthalocyanine) are used as epoxidation catalysts of cyclooctene in homogeneous and heterogeneous conditions by iodosylbenzene as an oxidant. Their catalytic activities have shown that the electron withdrawing groups on the phthalocyanine ring have a very small effect on stability of the catalyst during the reactions.


2016 ◽  
Vol 45 (18) ◽  
pp. 7875-7880 ◽  
Author(s):  
Tan L. H. Doan ◽  
Thong Q. Dao ◽  
Hai N. Tran ◽  
Phuong H. Tran ◽  
Thach N. Le

The catalytic activity of a highly porous and stable zirconium-based metal–organic framework in the benzoylation reaction was enhanced by microwave irradiation.


2019 ◽  
Vol 14 (12) ◽  
pp. 55
Author(s):  
Nguyễn Duy Khôi ◽  
Nguyễn Thanh Bình ◽  
Phan Thị Hoàng Oanh

The synthesis of Fe-MIL-101 material with the presence of H2BDC linker and iron (III) chloride achieving remarkable success is a result of solvothermal method. Catalytic activity works on the Friedel-Crafts benzoylation reaction of aromatic compounds and benzoyl chloride. In addition, Fe-MIL-101 is a heterogeneous catalyst which succeeds in not only shortening duration in a significant amount, but also increasing conversion with the assistance of the microwave irradiation compared with the conventional heating. Fe-MIL-101 would be a very potential alternative in place of unfavourable and dated iron (III) chloride homogeneous catalyst, due to its thermal stability, moreover, it can be recovered and reused after aqueous work-up.


2016 ◽  
Vol 19 (4) ◽  
pp. 177-184
Author(s):  
Hai Truong Nguyen ◽  
Phuong Hoang Tran

Friedel-Crafts acetylation is an important reaction in organic synthesis processes. Acetylation of indole derivatives with acetic anhydride as acylating reagent using Cu(OTf)2 as a catalyst has been investigated under microwave irradiation. Different from traditional Lewis acidic catalyst, Cu(OTf)2 was found to be an efficient catalyst for Friedel-Crafts acetylation of indoles under mild conditions. Moreover, Cu(OTf)2 was safe-to-handle, recovered and reused several times without significant loss of catalytic activity.


RSC Advances ◽  
2020 ◽  
Vol 10 (56) ◽  
pp. 34323-34332
Author(s):  
Junpeng Fan ◽  
Joakim Ekspong ◽  
Anumol Ashok ◽  
Sergey Koroidov ◽  
Eduardo Gracia-Espino

Production of nanostructured cobalt-doped MoS2 flakes with the CoMoS phase by microwave irradiation with improved catalytic activity towards hydrogen evolution.


ChemInform ◽  
2012 ◽  
Vol 43 (5) ◽  
pp. no-no
Author(s):  
Madhusudana Reddy M. Bhojegowd ◽  
Ashoka Siddaramanna ◽  
Anandakumar B. Shiddappa ◽  
Chandrappa G. Thimmanna ◽  
Mohamed A. Pasha

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