Triple bonds between iron and heavier group-14 elements in the AFe(CO)3− complexes (A = Ge, Sn, and Pb)

2019 ◽  
Vol 55 (40) ◽  
pp. 5685-5688 ◽  
Author(s):  
Jia-Qi Wang ◽  
Chaoxian Chi ◽  
Jun-Bo Lu ◽  
Luyan Meng ◽  
Mingbiao Luo ◽  
...  
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Main Group ◽  
Ion Source ◽  
Group Element ◽  
Laser Vaporization ◽  
Group 14 ◽  
Triple Bonds ◽  
Group 14 Elements ◽  
Anion Complexes

Heteronuclear transition-metal-main-group element carbonyl anion complexes of AFe(CO)3− (A = Ge, Sn, and Pb) are prepared using a laser vaporization supersonic ion source in the gas phase, which were studied by mass-selected infrared (IR) photodissociation spectroscopy.

Transition metal-mediated donor–acceptor coordination of low-oxidation state Group 14 element halides

2016 ◽  
Vol 45 (14) ◽  
pp. 6071-6078 ◽  
Author(s):  
Anindya K. Swarnakar ◽  
Michael J. Ferguson ◽  
Robert McDonald ◽  
Eric Rivard
Keyword(s):  
Transition Metal ◽  
Oxidation State ◽  
Bond Activation ◽  
Main Group ◽  
Group Element ◽  
Group 14 ◽  
Acidic Group ◽  
Main Group Element ◽  
Donor Acceptor ◽  
State Group

The main group element triggered C–H bond activation of a Rh-bound Cp ligand is reported. The key aspect of this transformation is the presence of a highly Lewis acidic Group 14 element site.

Catalytic Fluorination of Boron Compounds at a Bismuth Redox Platform

2019 ◽  
Author(s):  
Oriol Planas ◽  
Feng Wang ◽  
Markus Leutzsch ◽  
Josep Cornella
Keyword(s):  
Transition Metal ◽  
Main Group ◽  
Group Element ◽  
Oxidation States ◽  
Boron Compounds ◽  
Main Text ◽  
Main Group Element ◽  
Rational Ligand Design ◽  
Supplementary Material

The ability of bismuth to maneuver between different oxidation states in a catalytic redox cycle, mimicking the canonical organometallic steps associated to a transition metal, is an elusive and unprecedented approach in the field of homogeneous catalysis. Herein we present a catalytic protocol based on bismuth, a benign and sustainable main-group element, capable of performing every organometallic step in the context of oxidative fluorination of boron compounds; a territory reserved to transition metals. A rational ligand design featuring hypervalent coordination together with a mechanistic understanding of the fundamental steps, permitted a catalytic fluorination protocol based on a Bi(III)/Bi(V) redox couple, which represents a unique example where a main-group element is capable of outperforming its transition metal counterparts.<br>A main text and supplementary material have been attached as pdf files containing all the methodology, techniques and characterization of the compounds reported.<br>

scholarly journals On the Coordination Role of Pyridyl-Nitrogen in the Structural Chemistry of Pyridyl-Substituted Dithiocarbamate Ligands

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 286
Author(s):  
Edward R.T. Tiekink
Keyword(s):  
Transition Metal ◽  
Main Group ◽  
Group Element ◽  
Systematic Research ◽  
Pyridyl Nitrogen ◽  
General Observation ◽  
Supramolecular Architectures ◽  
Main Group Element ◽  
Metal Dithiocarbamates

A search of the Cambridge Structural Database was conducted for pyridyl-substituted dithiocarbamate ligands. This entailed molecules containing both an NCS2− residue and pyridyl group(s), in order to study their complexation behavior in their transition metal and main group element crystals, i.e., d- and p-block elements. In all, 73 different structures were identified with 30 distinct dithiocarbamate ligands. As a general observation, the structures of the transition metal dithiocarbamates resembled those of their non-pyridyl derivatives, there being no role for the pyridyl-nitrogen atom in coordination. While the same is true for many main group element dithiocarbamates, a far greater role for coordination of the pyridyl-nitrogen atoms was evident, in particular, for the heavier elements. The participation of pyridyl-nitrogen in coordination often leads to the formation of dimeric aggregates but also one-dimensional chains and two-dimensional arrays. Capricious behaviour in closely related species that adopted very different architectures is noted. Sometimes different molecules comprising the asymmetric-unit of a crystal behave differently. The foregoing suggests this to be an area in early development and is a fertile avenue for systematic research for probing further crystallization outcomes and for the rational generation of supramolecular architectures.

The Charge Transfer Approach to Heavier Main‐Group Element Radicals in Transition‐Metal Complexes

2017 ◽  
Vol 56 (41) ◽  
pp. 12741-12745 ◽  
Author(s):  
Gengwen Tan ◽  
Jing Li ◽  
Li Zhang ◽  
Chao Chen ◽  
Yue Zhao ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Group Element ◽  
Main Group Element
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