Palladium-catalyzed intramolecular transfer hydrogenation & cycloaddition of p-quinamine-tethered alkylidenecyclopropanes to synthesize perhydroindole scaffolds

2018 ◽  
Vol 54 (100) ◽  
pp. 14085-14088 ◽  
Author(s):  
Bo Cao ◽  
Yin Wei ◽  
Min Shi
Keyword(s):  
Transfer Hydrogenation ◽  
Palladium Catalyzed ◽  
Intramolecular Transfer

A facile Pd-catalyzed intramolecular transfer hydrogenation and cycloaddition of p-quinamine-tethered alkylidenecyclopropanes has been developed, giving rigid tricyclic perhydroindole skeletons in moderate to good yields.

Palladium-catalyzed simple and efficient hydrogenative cleavage of azo compounds using recyclable polymer-supported formate

2005 ◽  
Vol 83 (5) ◽  
pp. 517-520 ◽  
Author(s):  
Keelara Abiraj ◽  
Gejjalagere R Srinivasa ◽  
D Channe Gowda
Keyword(s):  
Functional Groups ◽  
Room Temperature ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Azo Compounds ◽  
Catalytic Transfer Hydrogenation ◽  
Palladium Catalyzed ◽  
Catalytic Transfer ◽  
Polymer Supported

Palladium-catalyzed room temperature transfer hydrogenation of azo compounds using recyclable polymer-supported formate as the hydrogen donor produces corresponding amine(s) in excellent yields (88%–98%). This method was found to be highly facile with selectivity over a number of other functional groups such as halogen, alkene, nitrile, carbonyl, amide, methoxy, and hydroxyl.Key words: azo compounds, catalytic transfer hydrogenation, polymer-supported formate, 10% Pd-C, amines.

Palladium-catalyzed transfer hydrogenation in alkaline aqueous medium

2000 ◽  
Vol 41 (41) ◽  
pp. 7847-7849 ◽  
Author(s):  
Jeffrey B Arterburn ◽  
Madhavi Pannala ◽  
Anicele M Gonzalez ◽  
Rebecca M Chamberlin
Keyword(s):  
Aqueous Medium ◽  
Transfer Hydrogenation ◽  
Palladium Catalyzed

ChemInform Abstract: Tetrahydroxydiboron-Mediated Palladium-Catalyzed Transfer Hydrogenation and Deuteriation of Alkenes and Alkynes Using Water as the Stoichiometric H or D Atom Donor.

ChemInform ◽  
2016 ◽  
Vol 47 (45) ◽  
Author(s):  
Steven P. Cummings ◽  
Thanh-Ngoc Le ◽  
Gilberto E. Fernandez ◽  
Lorenzo G. Quiambao ◽  
Benjamin J. Stokes
Keyword(s):  
Transfer Hydrogenation ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Transfer Hydrogenation in Alkaline Aqueous Medium.

ChemInform ◽  
2000 ◽  
Vol 31 (52) ◽  
pp. no-no
Author(s):  
Jeffrey B. Arterburn ◽  
Madhavi Pannala ◽  
Anicele M. Gonzalez ◽  
Rebecca M. Chamberlin
Keyword(s):  
Aqueous Medium ◽  
Transfer Hydrogenation ◽  
Palladium Catalyzed
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