Organic chelate-free and azido-rich metal clusters and coordination polymers from the use of Me3SiN3: a new synthetic route to complexes with beautiful structures and diverse magnetic properties

A new synthetic route to structurally novel and magnetically interesting 3d-metal azido clusters and coordination polymers is presented; the key reagent for the preparation of solely azido-bridged molecule-based species is the organic azide precursor Me3SiN3.