Electrochemical behaviors of Li-argyrodite-based all-solid-state batteries under deep-freezing conditions

2018 ◽  
Vol 54 (100) ◽  
pp. 14116-14119 ◽  
Author(s):  
Sungjun Choi ◽  
Minjae Jeon ◽  
Byung-Kook Kim ◽  
Byoung-In Sang ◽  
Hyoungchul Kim
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Electrochemical Behavior ◽  
Harsh Environments ◽  
Electrochemical Behaviors ◽  
Deep Freezing ◽  
Solid State Batteries ◽  
All Solid State Batteries

The electrochemical behavior of all-solid-state batteries in harsh environments was investigated and new insights for its low-temperature operation were provided.

Low temperature sintering of fully inorganic all-solid-state batteries – Impact of interfaces on full cell performance

2021 ◽  
Vol 482 ◽  
pp. 228905
Author(s):  
Martin Ihrig ◽  
Martin Finsterbusch ◽  
Chih-Long Tsai ◽  
Alexander M. Laptev ◽  
Chia-hao Tu ◽  
...  
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Cell Performance ◽  
Low Temperature Sintering ◽  
Full Cell ◽  
Solid State Batteries ◽  
All Solid State Batteries

Development of Solid Electrolytes for All-Solid-State Batteries

2019 ◽  
Vol 92 (11) ◽  
pp. 430-434
Author(s):  
Akitoshi HAYASHI ◽  
Atsushi SAKUDA ◽  
Masahiro TATSUMISAGO
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Operando Visualization of Morphological Dynamics in All-Solid-State Batteries

2019 ◽  
Author(s):  
Xiaohan Wu ◽  
Juliette Billaud ◽  
Iwan Jerjen ◽  
Federica Marone ◽  
Yuya Ishihara ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Rational Design ◽  
Morphological Evolution ◽  
Active Material ◽  
Composite Layer ◽  
Transference Number ◽  
Thermal Stabilities ◽  
Solid State Batteries ◽  
All Solid State Batteries

<div> <div> <div> <p>All-solid-state batteries are considered as attractive options for next-generation energy storage owing to the favourable properties (unit transference number and thermal stabilities) of solid electrolytes. However, there are also serious concerns about mechanical deformation of solid electrolytes leading to the degradation of the battery performance. Therefore, understanding the mechanism underlying the electro-mechanical properties in SSBs are essentially important. Here, we show three-dimensional and time-resolved measurements of an all-solid-state cell using synchrotron radiation x-ray tomographic microscopy. We could clearly observe the gradient of the electrochemical reaction and the morphological evolution in the composite layer. Volume expansion/compression of the active material (Sn) was strongly oriented along the thickness of the electrode. While this results in significant deformation (cracking) in the solid electrolyte region, we also find organized cracking patterns depending on the particle size and their arrangements. This study based on operando visualization therefore opens the door towards rational design of particles and electrode morphology for all-solid-state batteries. </p> </div> </div> </div>

scholarly journals Structural Investigation of NCM-Cathode-LLZO-Electrolyte Composites as Promising Candidates for All-Solid-State Batteries Using (Cryo) STEM and PED

2021 ◽  
Vol 27 (S1) ◽  
pp. 1978-1979
Author(s):  
Thomas Demuth ◽  
Till Fuchs ◽  
Anuj Pokle ◽  
Andreas Beyer ◽  
Jürgen Janek ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Investigation ◽  
Solid State Batteries ◽  
All Solid State Batteries
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