An integrated immobilization strategy manipulates dual active centers to boost enantioselective tandem reactions

2018 ◽  
Vol 54 (94) ◽  
pp. 13244-13247 ◽  
Author(s):  
Xiaomin Shu ◽  
Ronghua Jin ◽  
Zhongrui Zhao ◽  
Tanyu Cheng ◽  
Guohua Liu
Keyword(s):  
High Efficiency ◽  
Suzuki Coupling ◽  
Bifunctional Catalyst ◽  
Transfer Hydrogenation ◽  
Tandem Reactions ◽  
Asymmetric Transfer Hydrogenation ◽  
Active Centers

A bifunctional catalyst assembled by dual species manipulation presents high efficiency in Suzuki coupling-asymmetric transfer hydrogenation tandem reactions.

Facile assembly of bifunctional, magnetically retrievable mesoporous silica for enantioselective cascade reactions

2019 ◽  
Vol 55 (90) ◽  
pp. 13578-13581 ◽  
Author(s):  
Zhongrui Zhao ◽  
Fengwei Chang ◽  
Tao Wang ◽  
Lijian Wang ◽  
Lingbo Zhao ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Cross Coupling ◽  
Bifunctional Catalyst ◽  
Cascade Reactions ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Aromatic Alcohols ◽  
Hydrogenation Reactions ◽  
Successive Reduction

A magnetically recyclable bifunctional catalyst enables synergistic Suzuki cross-coupling/asymmetric transfer hydrogenation and successive reduction/asymmetric transfer hydrogenation reactions for the preparation of chiral aromatic alcohols.

Integration of multiple active sites on large-pore mesoporous silica for enantioselective tandem reactions

2017 ◽  
Vol 53 (10) ◽  
pp. 1638-1641 ◽  
Author(s):  
Xuelin Xia ◽  
Jingjing Meng ◽  
Hanxin Wu ◽  
Tanyu Cheng ◽  
Guohua Liu
Keyword(s):  
Mesoporous Silica ◽  
Heterogeneous Catalyst ◽  
Active Sites ◽  
Catalytic Performance ◽  
Transfer Hydrogenation ◽  
Tandem Reactions ◽  
Asymmetric Transfer Hydrogenation ◽  
Large Pore

A Au/Ru-bifunctionalized heterogeneous catalyst exhibited high catalytic performance in enantioselective tandem hydration-asymmetric transfer hydrogenation of haloalkynes to chiral halohydrins.

ChemInform Abstract: Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2Hydrogenation.

ChemInform ◽  
2012 ◽  
Vol 43 (12) ◽  
pp. no-no
Author(s):  
Taichiro Touge ◽  
Tomohiko Hakamata ◽  
Hideki Nara ◽  
Tohru Kobayashi ◽  
Noboru Sayo ◽  
...  
Keyword(s):  
Bifunctional Catalyst ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

Enantioselective tandem reaction over a site-isolated bifunctional catalyst

2016 ◽  
Vol 52 (35) ◽  
pp. 6005-6008 ◽  
Author(s):  
Jianyou Xu ◽  
Tanyu Cheng ◽  
Kun Zhang ◽  
Ziyun Wang ◽  
Guohua Liu
Keyword(s):  
Mesoporous Silica ◽  
Active Site ◽  
Bifunctional Catalyst ◽  
Transfer Hydrogenation ◽  
Tandem Reaction ◽  
Sonogashira Coupling ◽  
Asymmetric Transfer Hydrogenation ◽  
One Pot ◽  
The One ◽  
A Site

An active site-isolated organoruthenium-/organopalladium-functionalized yolk–shell-structured mesoporous silica is developed and its application in the one-pot enantioselective tandem Sonogashira coupling–asymmetric transfer hydrogenation of haloacetophenones and arylacetylenes to various chiral conjugated alkynols is investigated.

Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2Hydrogenation

2011 ◽  
Vol 133 (38) ◽  
pp. 14960-14963 ◽  
Author(s):  
Taichiro Touge ◽  
Tomohiko Hakamata ◽  
Hideki Nara ◽  
Tohru Kobayashi ◽  
Noboru Sayo ◽  
...  
Keyword(s):  
Bifunctional Catalyst ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation
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