scholarly journals Selective nitrogen doping of graphene oxide by laser irradiation for enhanced hydrogen evolution activity

2018 ◽  
Vol 54 (97) ◽  
pp. 13726-13729 ◽  
Author(s):  
Wenjing Zheng ◽  
Yan Zhang ◽  
Kaiyang Niu ◽  
Tao Liu ◽  
Karen Bustillo ◽  
...  

Selective nitrogen doping of graphene oxide with a high pyridinic N ratio for enhanced hydrogen evolution activity was achieved by using a laser irradiation method.

ACS Catalysis ◽  
2021 ◽  
pp. 4486-4497
Author(s):  
Jiayi Qin ◽  
Cong Xi ◽  
Rui Zhang ◽  
Tao Liu ◽  
Peichao Zou ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 662 ◽  
Author(s):  
Guangsheng Liu ◽  
Kunyapat Thummavichai ◽  
Xuefeng Lv ◽  
Wenting Chen ◽  
Tingjun Lin ◽  
...  

Molybdenum disulfide (MoS2) has been universally demonstrated to be an effective electrocatalytic catalyst for hydrogen evolution reaction (HER). However, the low conductivity, few active sites and poor stability of MoS2-based electrocatalysts hinder its hydrogen evolution performance in a wide pH range. The introduction of other metal phases and carbon materials can create rich interfaces and defects to enhance the activity and stability of the catalyst. Herein, a new defect-rich heterogeneous ternary nanocomposite consisted of MoS2, NiS and reduced graphene oxide (rGO) are synthesized using ultrathin αNi(OH)2 nanowires as the nickel source. The MoS2/rGO/NiS-5 of optimal formulation in 0.5 M H2SO4, 1.0 M KOH and 1.0 M PBS only requires 152, 169 and 209 mV of overpotential to achieve a current density of 10 mA cm−2 (denoted as η10), respectively. The excellent HER performance of the MoS2/rGO/NiS-5 electrocatalyst can be ascribed to the synergistic effect of abundant heterogeneous interfaces in MoS2/rGO/NiS, expanded interlayer spacings, and the addition of high conductivity graphene oxide. The method reported here can provide a new idea for catalyst with Ni-Mo heterojunction, pH-universal and inexpensive hydrogen evolution reaction electrocatalyst.


Author(s):  
R.V. Tolentino-Hernandez ◽  
F.A. Garcia-Pastor ◽  
H. Baez-Medina ◽  
E. Jimenez-Melero ◽  
F. Caballero-Briones

2020 ◽  
Vol 49 (12) ◽  
pp. 20201064-20201064
Author(s):  
王飞跃 Feiyue Wang ◽  
邹婷婷 Tingting Zou ◽  
辛巍 Wei Xin ◽  
杨建军 Jianjun Yang

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