Cu3L2 metal–organic cages for A3-coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery

2018 ◽  
Vol 54 (82) ◽  
pp. 11550-11553 ◽  
Author(s):  
Gong-Jun Chen ◽  
Chao-Qun Chen ◽  
Xue-Tian Li ◽  
Hui-Chao Ma ◽  
Yu-Bin Dong

A novel Cu3L2 metal–organic cage, which features coordination interaction triggered solubility, can be a highly active and reusable catalyst to homogeneously catalyse the one-pot aldehyde–alkyne–amine A3-coupling reaction.

2017 ◽  
Vol 41 (15) ◽  
pp. 7108-7115 ◽  
Author(s):  
Hong-Yan Zhang ◽  
Xiao-Peng Hao ◽  
Li-Ping Mo ◽  
Sha-Sha Liu ◽  
Wen-Bo Zhang ◽  
...  

A novel magnetic metal–organic framework, NiFe2O4@MOF-5, was prepared and demonstrated to be a highly efficient catalyst for the one-pot three-component reaction of aldehyde, indole, and kojic acid.


2019 ◽  
Vol 55 (42) ◽  
pp. 5898-5901 ◽  
Author(s):  
Houbing Zou ◽  
Jinyu Dai ◽  
Runwei Wang

We design and prepare a highly active and stable nanoreactor by encapsulating mesoporous metal nanoparticles for efficient production of α,β-unsaturated ketones via a one-pot oxidative coupling reaction.


2017 ◽  
Vol 6 (6) ◽  
pp. 712-719 ◽  
Author(s):  
Bhoomireddy Rajendra Prasad Reddy ◽  
Peddiahgari Vasu Govardhana Reddy ◽  
Muthukonda V. Shankar ◽  
Bijivemula N. Reddy

RSC Advances ◽  
2014 ◽  
Vol 4 (79) ◽  
pp. 42155-42158 ◽  
Author(s):  
Siyavash Kazemi Movahed ◽  
Noushin Farajinia Lehi ◽  
Minoo Dabiri

A novel gold nanoparticle supported on graphene oxide with ionic liquid framework was used as a highly active and recyclable catalyst for novel domino oxidative A3-coupling reaction.


2018 ◽  
Vol 33 (1) ◽  
pp. e4679 ◽  
Author(s):  
Mohammad Ali Ghasemzadeh ◽  
Boshra Mirhosseini-Eshkevari ◽  
Mohammad Hossein Abdollahi-Basir

RSC Advances ◽  
2014 ◽  
Vol 4 (25) ◽  
pp. 13093-13107 ◽  
Author(s):  
Liu Lili ◽  
Zhang Xin ◽  
Rang Shumin ◽  
Yang Ying ◽  
Dai Xiaoping ◽  
...  

Homochiral MOFs were engineered using postsynthetic modification and a one-pot synthetic strategy. l-Proline functionalized IRMOF-3 show high ee for aldol reaction. Gold functionalized CUP-1 catalysts are highly efficient for the A3 coupling reaction.


2018 ◽  
Author(s):  
Huong T. D. Nguyen ◽  
Y B. N. Tran ◽  
Hung N. Nguyen ◽  
Tranh C. Nguyen ◽  
Felipe Gándara ◽  
...  

<p>Three novel lanthanide metal˗organic frameworks (Ln-MOFs), namely MOF-590, -591, and -592 were constructed from a naphthalene diimide tetracarboxylic acid. Gas adsorption measurements of MOF-591 and -592 revealed good adsorption of CO<sub>2</sub> (low pressure, at room temperature) and moderate CO<sub>2</sub> selectivity over N<sub>2</sub> and CH<sub>4</sub>. Accordingly, breakthrough measurements were performed on a representative MOF-592, in which the separation of CO<sub>2</sub> from binary mixture containing N<sub>2</sub> and CO<sub>2</sub> was demonstrated without any loss in performance over three consecutive cycles. Moreover, MOF-590, MOF-591, and MOF-592 exhibited catalytic activity in the one-pot synthesis of styrene carbonate from styrene and CO<sub>2</sub> under mild conditions (1 atm CO<sub>2</sub>, 80 °C, and solvent-free). Among the new materials, MOF-590 revealed a remarkable efficiency with exceptional conversion (96%), selectivity (95%), and yield (91%). </p><br>


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