Controlled polymerizations using metal–organic frameworks

2018 ◽  
Vol 54 (84) ◽  
pp. 11843-11856 ◽  
Author(s):  
Shuto Mochizuki ◽  
Takashi Kitao ◽  
Takashi Uemura
Keyword(s):  
Metal Organic Frameworks ◽  
Short Review ◽  
Recent Developments ◽  
Metal Organic

This short review focuses on recent developments in polymerization reactions using metal–organic frameworks (MOFs).

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Elucidation of flexible metal-organic frameworks: Research progresses and recent developments

2019 ◽  
Vol 389 ◽  
pp. 161-188 ◽  
Author(s):  
Jae Hwa Lee ◽  
Sungeun Jeoung ◽  
Yongchul G. Chung ◽  
Hoi Ri Moon
Keyword(s):  
Metal Organic Frameworks ◽  
Recent Developments ◽  
Metal Organic ◽  
Flexible Metal

scholarly journals From Metal-Organic Framework Powders to Shaped Solids: Recent Developments and Challenges

2021 ◽  
Author(s):  
Bakytzhan Yeskendir ◽  
Jean-Philippe Dacquin ◽  
Yannick Lorgouilloux ◽  
Christian Courtois ◽  
Sebastien Royer ◽  
...  
Keyword(s):  
Porous Structure ◽  
Porous Materials ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
The Past ◽  
Recent Developments ◽  
Metal Organic ◽  
Organic Framework

Metal-organic frameworks represent a class of porous materials which developed considerably over the past few years. Their porous structure makes them outperforming conventional adsorbents in hot topics such as dihydrogen...

scholarly journals Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition

Inorganics ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 81
Author(s):  
Alessia Tombesi ◽  
Claudio Pettinari
Keyword(s):  
Carbon Dioxide ◽  
Coordination Polymers ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Metal Species ◽  
Olefin Epoxidation ◽  
Crystalline Materials ◽  
Recent Developments ◽  
Metal Organic ◽  
New Research

Metal–organic frameworks (MOFs) are a family of porous crystalline materials that serve in some cases as versatile platforms for catalysis. In this review, we overview the recent developments about the use of these species as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddition. We report the most important results obtained in this field relating them to the presence of specific organic linkers, metal nodes or clusters and mixed-metal species. Recent advances obtained with MOF nanocomposites were also described. Finally we compare the results and summarize the major insights in specific Tables, outlining the major challenges for this emerging field. This work could promote new research aimed at producing coordination polymers and MOFs able to catalyse a broader range of CO2 consuming reactions.

Metal–organic frameworks: a future toolbox for biomedicine?

2020 ◽  
Vol 49 (24) ◽  
pp. 9121-9153
Author(s):  
Ricardo F. Mendes ◽  
Flávio Figueira ◽  
José P. Leite ◽  
Luís Gales ◽  
Filipe A. Almeida Paz
Keyword(s):  
Metal Organic Frameworks ◽  
Present Review ◽  
Recent Developments ◽  
Metal Organic ◽  
Biological Field

The present review focuses on the use of Metal–Organic Frameworks, (MOFs) highlighting the most recent developments in the biological field and as bio-sensors.

Rational construction of metal–organic frameworks for heterogeneous catalysis

2014 ◽  
Vol 1 (10) ◽  
pp. 721-734 ◽  
Author(s):  
Sha Ou ◽  
Chuan-De Wu
Keyword(s):  
Heterogeneous Catalysis ◽  
Catalytic Properties ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Short Review ◽  
Metal Organic ◽  
Rational Construction ◽  
Designed Synthesis ◽  
Organic Framework

The recently developed strategies on designed synthesis of porous metal–organic framework catalysts and their interesting catalytic properties are summarized in this short review.

Luminescent triphenylamine-based metal–organic frameworks: recent advances in nitroaromatics detection

2020 ◽  
Vol 49 (37) ◽  
pp. 12929-12939
Author(s):  
Zhi-Qiang Shi ◽  
Ning-Ning Ji ◽  
Hai-Liang Hu
Keyword(s):  
Metal Organic Frameworks ◽  
Nitroaromatic Compounds ◽  
Recent Advances ◽  
Efficient Detection ◽  
Recent Developments ◽  
Metal Organic

This review focuses on recent developments on the luminescent triphenylamine-based MOFs for the efficient detection of nitroaromatic compounds (NACs).

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