Copper-catalyzed amination of an α-C(sp3)–H bond in inactivated ethers to synthesize α-aminonitriles

2018 ◽  
Vol 54 (78) ◽  
pp. 11033-11036 ◽  
Author(s):  
Zaifeng Yuan ◽  
Chunyu Zhu ◽  
Zhixian Ma ◽  
Chengfeng Xia
Keyword(s):  
Ring Opening ◽  
Cyclic Ethers ◽  
Cyanation Reaction

A copper-catalyzed functionalization of inert cyclic ethers was developed to provide α-aminonitriles via a cascade oxidation/amination/ring-opening/cyanation reaction.

Ring-opening polymerization of cyclic ethers initiated by benzazaphosphole-W(CO)5/silver hexafluoroantimonate

2013 ◽  
Vol 52 (5) ◽  
pp. 664-670 ◽  
Author(s):  
Mohammed Ghalib ◽  
Sergej Lysenko ◽  
Peter G. Jones ◽  
Joachim W. Heinicke
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Cyclic Ethers

Ring-opening spontaneous alternating copolymerization of a dithiadiphosphetane disulfide with cyclic ethers

1983 ◽  
Vol 10 (11-12) ◽  
pp. 491-496 ◽  
Author(s):  
Shiro Kobayashi ◽  
Tak Yuen Chow ◽  
Takeo Saegusa
Keyword(s):  
Ring Opening ◽  
Cyclic Ethers ◽  
Alternating Copolymerization

ChemInform Abstract: Cobalt-Catalyzed Ring-Opening Carbonylation of Cyclic Ethers Using N-(Trimethylsilyl)amines.

ChemInform ◽  
1990 ◽  
Vol 21 (10) ◽  
Author(s):  
Y. TSUJI ◽  
M. KOBAYASHI ◽  
F. OKUDA ◽  
Y. WATANABE
Keyword(s):  
Ring Opening ◽  
Cyclic Ethers

scholarly journals Rapid transformation of sulfinate salts into sulfonates promoted by a hypervalent iodine(III) reagent

2018 ◽  
Vol 14 ◽  
pp. 1203-1207 ◽  
Author(s):  
Elsa Deruer ◽  
Vincent Hamel ◽  
Samuel Blais ◽  
Sylvain Canesi
Keyword(s):  
Ring Opening ◽  
Hypervalent Iodine ◽  
Cyclic Ethers ◽  
Reaction Conditions ◽  
Alternative Method ◽  
Aromatic Systems ◽  
Mediated Oxidation ◽  
Rapid Transformation

An alternative method for forming sulfonates through hypervalent iodine(III) reagent-mediated oxidation of sodium sulfinates has been developed. This transformation involves trapping reactive sulfonium species using alcohols. With additional optimization of the reaction conditions, the method appears extendable to other nucleophiles such as electron-rich aromatic systems or cyclic ethers through a ring opening pathway.

Domino ring opening and selective O/S-alkylation of cyclic ethers and thioethers

2020 ◽  
Author(s):  
Manickam Bakthadoss ◽  
Vishal Agarwal ◽  
Thirupathi Reddy Tadiparthi ◽  
Mushaf Mohammad
Keyword(s):  
Ring Opening ◽  
Cyclic Ethers

Ring Opening of Biomass-Derived Cyclic Ethers to Dienes over Silica/Alumina

ACS Catalysis ◽  
2017 ◽  
Vol 7 (8) ◽  
pp. 5248-5256 ◽  
Author(s):  
Mrunmayi D. Kumbhalkar ◽  
J. Scott Buchanan ◽  
George W. Huber ◽  
James A. Dumesic
Keyword(s):  
Ring Opening ◽  
Cyclic Ethers ◽  
Silica Alumina
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