Palladium-catalyzed aerobic oxidative carbonylation of alkynes with amines: a general access to substituted maleimides

2018 ◽  
Vol 54 (76) ◽  
pp. 10710-10713 ◽  
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Ralf Jackstell ◽  
Matthias Beller

A catalytic oxidative carbonylation reaction was developed for the synthesis of polysubstituted maleimides from alkynes and amines with air as a green oxidant.

1991 ◽  
Vol 56 (3) ◽  
pp. 663-672 ◽  
Author(s):  
Curtis B. Anderson ◽  
Rade Marković

The influence of temperature and carbon monoxide pressure on the course of oxidative carbonylation reaction of 1,5-cyclooctadiene in the presence of the palladium(II) salts as a catalyst, was investigated.


2015 ◽  
Vol 51 (10) ◽  
pp. 1905-1907 ◽  
Author(s):  
Yu Wang ◽  
Xu Meng ◽  
Yuting Yang ◽  
Lutao Zhang ◽  
Shuaibo Guo ◽  
...  

A novel palladium-catalyzed oxidative carbonylation reaction was developed via the carbon monoxide insertions between the amine group and the carbonyl group to realize the intramolecular cyclization, which provides efficient access to 1,3,4-oxadiazol-2(3H)-ones with a wide range of substrates under mild conditions, resulting in good to excellent yields.


ChemInform ◽  
2014 ◽  
Vol 45 (20) ◽  
pp. no-no
Author(s):  
Ming Chen ◽  
Zhi-Hui Ren ◽  
Yao-Yu Wang ◽  
Zheng-Hui Guan

2014 ◽  
Vol 53 (9) ◽  
pp. 2443-2446 ◽  
Author(s):  
Wu Li ◽  
Chao Liu ◽  
Heng Zhang ◽  
Keyin Ye ◽  
Guanghui Zhang ◽  
...  

2019 ◽  
Vol 43 (46) ◽  
pp. 18072-18078 ◽  
Author(s):  
Yuvraj A. Kolekar ◽  
Bhalchandra M. Bhanage

Palladium-catalyzed oxidative cross double carbonylation reaction between tertiary amines and alcohols using oxidant O2 and KI as the additive affords oxamates. Oxamate are as a intermediate in biological active compound and glycol synthesis.


2020 ◽  
Vol 18 (8) ◽  
pp. 1612-1622 ◽  
Author(s):  
Attoor Chandrasekhar ◽  
Sethuraman Sankararaman

A methodology that involves the Pd-catalyzed direct C(sp2)–H bond carbonylation of the C2 position of indole has been introduced for the synthesis of indolo[1,2-a]quinoxalin-6(5H)-ones.


2020 ◽  
Vol 7 (4) ◽  
pp. 697-701 ◽  
Author(s):  
Shoucai Wang ◽  
Siyu Zhang ◽  
Meichen Liu ◽  
Jiawang Zang ◽  
Guangbin Jiang ◽  
...  

A palladium-catalyzed C3-selective C–H oxidative carbonylation for the synthesis of various esters from imidazo[1,2-a]pyridines and CO with high efficiency and high atom economy has been developed.


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