scholarly journals Trends in the valence band electronic structures of mixed uranium oxides

2018 ◽  
Vol 54 (70) ◽  
pp. 9757-9760 ◽  
Author(s):  
Kristina O. Kvashnina ◽  
Piotr M. Kowalski ◽  
Sergei M. Butorin ◽  
Gregory Leinders ◽  
Janne Pakarinen ◽  
...  
Keyword(s):  
Valence Band ◽  
Computational Methods ◽  
Electronic Structures ◽  
Uranium Oxides ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Scattering

The valence band electronic structures of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, and β-UO3) have been studied using the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and computational methods.

scholarly journals Resonant inelastic soft-x-ray scattering from valence-band excitations in3d0compounds

1997 ◽  
Vol 55 (7) ◽  
pp. 4242-4249 ◽  
Author(s):  
S. M. Butorin ◽  
J.-H. Guo ◽  
M. Magnuson ◽  
J. Nordgren
Keyword(s):  
Valence Band ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Scattering

Electronic structures ofLiFePO4andFePO4studied using resonant inelastic x-ray scattering

2006 ◽  
Vol 73 (20) ◽  
Author(s):  
A. Hunt ◽  
W.-Y. Ching ◽  
Y.-M. Chiang ◽  
A. Moewes
Keyword(s):  
Electronic Structures ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Scattering

Cobalt-to-vanadium charge transfer in polyoxometalate water oxidation catalysts revealed by 2p3d resonant inelastic X-ray scattering

2018 ◽  
Vol 20 (6) ◽  
pp. 4554-4562 ◽  
Author(s):  
Boyang Liu ◽  
Elliot N. Glass ◽  
Ru-Pan Wang ◽  
Yi-Tao Cui ◽  
Yoshihisa Harada ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Charge Transfer ◽  
Water Oxidation ◽  
Electronic Structures ◽  
Oxidation Catalysts ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Scattering

2p3d RIXS spectra reveal electronic structures ofCo4V2WOC, which offers insights into its enhanced catalytic activity thanCo4P2WOC.

Soft X-Ray Emission and Resonant Inelastic X-Ray Scattering Studies of Transition Metal Oxides.

2002 ◽  
Vol 755 ◽  
Author(s):  
Kevin E. Smith ◽  
Cormac McGuinness ◽  
James Downes ◽  
Philip Ryan ◽  
Dongfeng Fu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Valence Band ◽  
Transition Metal Oxides ◽  
Partial Density ◽  
Narrow Gap ◽  
Metal Insulator ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Scattering

ABSTRACTThis paper discusses the application of soft x-ray emission and resonant inelastic x-ray scattering as probes of the electronic structure of transition metal oxides. The results of studies on the narrow gap insulator CdO, and the Mott-Hubbard oxide Cr-doped V2O3, are reported. The O 2p valence band partial density of states for CdO has been measured, and emission due to the hybridization of the O 2p valence band states with Cd 4d shallow core level has been observed. For Cr-doped V2O3, the temperature induced metal-insulator transition in samples with 1.5% Cr was observed using soft x-ray emission, and both charge transfer and dipole forbidden d-d excitations were observed using resonant inelastic x-ray scattering.

Microtubule nucleation sequence studied by time-resolved x-ray scattering and electron microscopy

1983 ◽  
Vol 41 ◽  
pp. 766-767
Author(s):  
Eva-Maria Mandelkow ◽  
Eckhard Mandelkow ◽  
Joan Bordas
Keyword(s):  
Electron Microscopy ◽  
Dynamic Equilibrium ◽  
Time Resolved ◽  
X Ray ◽  
Additional Information ◽  
X Ray Scattering ◽  
Low Concentrations ◽  
Microtubule Growth ◽  
Ray Patterns ◽  
Ray Scattering

When a solution of microtubule protein is changed from non-polymerising to polymerising conditions (e.g. by temperature jump or mixing with GTP) there is a series of structural transitions preceding microtubule growth. These have been detected by time-resolved X-ray scattering using synchrotron radiation, and they may be classified into pre-nucleation and nucleation events. X-ray patterns are good indicators for the average behavior of the particles in solution, but they are difficult to interpret unless additional information on their structure is available. We therefore studied the assembly process by electron microscopy under conditions approaching those of the X-ray experiment. There are two difficulties in the EM approach: One is that the particles important for assembly are usually small and not very regular and therefore tend to be overlooked. Secondly EM specimens require low concentrations which favor disassembly of the particles one wants to observe since there is a dynamic equilibrium between polymers and subunits.

Time-Resolved Cryo-Electron Microscopy of Oscillating Microtubules

1990 ◽  
Vol 48 (1) ◽  
pp. 502-503
Author(s):  
Eva-Maria Mandelkow ◽  
Ron Milligan
Keyword(s):  
Electron Microscopy ◽  
Dynamic Instability ◽  
Entire Solution ◽  
Reaction Scheme ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Scattering ◽  
A Chain ◽  
Ray Scattering

Microtubules form part of the cytoskeleton of eukaryotic cells. They are hollow libers of about 25 nm diameter made up of 13 protofilaments, each of which consists of a chain of heterodimers of α-and β-tubulin. Microtubules can be assembled in vitro at 37°C in the presence of GTP which is hydrolyzed during the reaction, and they are disassembled at 4°C. In contrast to most other polymers microtubules show the behavior of “dynamic instability”, i.e. they can switch between phases of growth and phases of shrinkage, even at an overall steady state [1]. In certain conditions an entire solution can be synchronized, leading to autonomous oscillations in the degree of assembly which can be observed by X-ray scattering (Fig. 1), light scattering, or electron microscopy [2-5]. In addition such solutions are capable of generating spontaneous spatial patterns [6].In an earlier study we have analyzed the structure of microtubules and their cold-induced disassembly by cryo-EM [7]. One result was that disassembly takes place by loss of protofilament fragments (tubulin oligomers) which fray apart at the microtubule ends. We also looked at microtubule oscillations by time-resolved X-ray scattering and proposed a reaction scheme [4] which involves a cyclic interconversion of tubulin, microtubules, and oligomers (Fig. 2). The present study was undertaken to answer two questions: (a) What is the nature of the oscillations as seen by time-resolved cryo-EM? (b) Do microtubules disassemble by fraying protofilament fragments during oscillations at 37°C?

X-ray scattering by 1D molecular Guinier-Preston zones in ordered smectic phases

1992 ◽  
Vol 2 (6) ◽  
pp. 899-913 ◽  
Author(s):  
Patrick Davidson ◽  
Elisabeth Dubois-Violette ◽  
Anne-Marie Levelut ◽  
Brigitte Pansu
Keyword(s):  
X Ray ◽  
X Ray Scattering ◽  
Smectic Phases ◽  
Ray Scattering
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