One-pot selective N-formylation of nitroarenes to formamides catalyzed by core–shell structured cobalt nanoparticles

2018 ◽  
Vol 54 (64) ◽  
pp. 8913-8916 ◽  
Author(s):  
Xiaosu Dong ◽  
Zhaozhan Wang ◽  
Yanan Duan ◽  
Yong Yang

A first heterogeneous non-noble cobalt catalyst for one-pot direct N-formylation of nitroarenes exhibiting high activity with a broad substrate scope under mild conditions is synthesised. It is easily separated with good recyclability.

2019 ◽  
Vol 21 (16) ◽  
pp. 4334-4340 ◽  
Author(s):  
Kang-kang Sun ◽  
Jia-lin Sun ◽  
Guo-Ping Lu ◽  
Chun Cai

A cobalt catalyst derived from a unique core–shell structure based on hollow ZIF-8 and ZIF-67 is prepared for the synthesis of nitriles from alcohols in water under mild conditions.


2020 ◽  
Vol 44 (15) ◽  
pp. 5661-5665
Author(s):  
Hongbo Yu ◽  
Zhengtong Guo ◽  
Chunzheng Wu ◽  
Shujian Wang ◽  
Bin Li ◽  
...  

The combination of the Au–Fe2O3 phase and core–shell structure helps in achieving high activity and good thermal stability.


2016 ◽  
Vol 4 (9) ◽  
pp. 3278-3286 ◽  
Author(s):  
C. Engelbrekt ◽  
N. Šešelj ◽  
R. Poreddy ◽  
A. Riisager ◽  
J. Ulstrup ◽  
...  

Atomically thin platinum shells on gold nanoparticles (NPs) are synthesized in one pot under mild conditions. The core-shell NPs exhibit excellent catalysis for energy related processes such as electrochemical oxidation of biofuels, aromatic ring hydrogenation, and γ-valerolactone production.


Author(s):  
Yu Jiang ◽  
Shanshan Gao ◽  
Gongchen Xu ◽  
Xiaoming Song

Porous and amorphous CoSx(OH)y core–shell nanoneedles covered by numerous ultra-thin small nanosheets are synthesized successfully on Ti-mesh, and act as a high activity and stability bifunctional catalyst for urea electrolysis.


Author(s):  
Philipp Natho ◽  
Zeyu Yang ◽  
Lewis Allen ◽  
Juliette Rey ◽  
Andrew J P White ◽  
...  

A transition-metal-free strategy for the synthesis of 2-(cyclobut-1-en-1-yl)-1H-indoles under mild conditions is described herein. A series of substituted 2-(cyclobut-1-en-1-yl)-1H-indoles are accessed by a one-pot cyclobutenylation/deprotection cascade from N-Boc protected indoles....


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