Fine-tuning the assemblies of carbon nanodots and porphyrins

2018 ◽  
Vol 54 (82) ◽  
pp. 11642-11644 ◽  
Author(s):  
Tobias Scharl ◽  
Alejandro Cadranel ◽  
Philipp Haines ◽  
Volker Strauss ◽  
Sarah Bernhardt ◽  
...  

We present charge-transfer assemblies of electron accepting, pressure-synthesized carbon nanodots (pCNDs) and an electron donating porphyrin.

2017 ◽  
Vol 5 (43) ◽  
pp. 8591-8599 ◽  
Author(s):  
Dominik H. Hasenöhrl ◽  
Avishek Saha ◽  
Volker Strauss ◽  
Leonie Wibmer ◽  
Stefanie Klein ◽  
...  

Carbon nanodots are used to stabilize gold-nanoclusters. Charge-transfer interactions between carbon nanodots and gold were detected by transient absorption spectroscopy.


2019 ◽  
Vol 52 (4) ◽  
pp. 955-963 ◽  
Author(s):  
Alejandro Cadranel ◽  
Johannes T. Margraf ◽  
Volker Strauss ◽  
Timothy Clark ◽  
Dirk M. Guldi

2008 ◽  
Vol 77 (15) ◽  
Author(s):  
H. Shiozawa ◽  
T. Pichler ◽  
C. Kramberger ◽  
A. Grüneis ◽  
M. Knupfer ◽  
...  

2017 ◽  
Vol 5 (9) ◽  
pp. 2415-2424 ◽  
Author(s):  
K. Pilarczyk ◽  
K. Lewandowska ◽  
K. Mech ◽  
M. Kawa ◽  
M. Gajewska ◽  
...  

The interplay between titanium dioxide and two electron acceptors (graphene oxide and chloranilic acid) results in the fine-tuning of photoelectrochemical properties of the ternary nanocomposite.


CrystEngComm ◽  
2016 ◽  
Vol 18 (11) ◽  
pp. 1987-1995 ◽  
Author(s):  
Xin Ding ◽  
Matti J. Tuikka ◽  
Pipsa Hirva ◽  
Vadim Yu. Kukushkin ◽  
Alexander S. Novikov ◽  
...  

The current paper introduces the use of stable carbonyl containing ruthenium complexes, [Ru(bpy)(CO)2X2] (X = Cl, Br, I), as halogen bond acceptors for a I2halogen bond donor.


2019 ◽  
Vol 20 (3) ◽  
pp. 828-836
Author(s):  
Kaixun Tian ◽  
Jing Xiao ◽  
Jian Shen ◽  
He Zhao

Abstract In the past few decades, heavy metal pollution, such as As(V), has become an important issue for aqueous environment safety. For reasons of practical feasibility and cost-effectiveness, adsorption has been widely used in the water treatment and reuse community, with rapid development of adsorbents. However, the precise control of the electronic configuration of the adsorbents' sites to enhance adsorption performance is largely unexplored. In this study, to demonstrate the effect of electronic configuration on adsorption performance, we synthesized granular activated carbon (GAC) supported Fe-based hydroxides adsorbents by varying the valence state in transition metals. Furthermore, the adsorbents are characterized by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM) to identify surface structure and morphological properties. Adsorptive performance studies show that the adsorption capacity and arsenic removal efficiency of Fe(II)-GAC are twice those of Fe(III)-GAC, as a matter of charge transfer between adsorbents and cationic pollution (such as Fe-O and As species). Finally, PO43− was selected as a control sample to confirm the rationality of the removal mechanism. Collectively, fine-tuning of the electronic configuration from charge transfer will not only benefit heavy metal removal channels, but also supply fundamental information for adsorbents design for organics removal.


2019 ◽  
Vol 55 (22) ◽  
pp. 3223-3226 ◽  
Author(s):  
Tobias Scharl ◽  
Andrés Ferrer-Ruiz ◽  
Adrián Saura-Sanmartín ◽  
Laura Rodríguez-Pérez ◽  
M. Ángeles Herranz ◽  
...  

Excited-state investigations with graphene quantum dots reveal slower charge recombination than with carbon nanodots in tetrathiafulvalene nanoconjugates.


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