scholarly journals Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks

2018 ◽  
Vol 54 (51) ◽  
pp. 6999-7002 ◽  
Author(s):  
Athena M. Fidelli ◽  
Bahar Karadeniz ◽  
Ashlee J. Howarth ◽  
Igor Huskić ◽  
Luzia S. Germann ◽  
...  

Dodecanuclear zirconium precursor enables a rapid and efficient mechanochemical synthesis of advanced MOFs NU-901 and UiO-67 with surface areas of up to 2250 m2 g−1.

2010 ◽  
Vol 22 (18) ◽  
pp. 5216-5221 ◽  
Author(s):  
Maria Klimakow ◽  
Peter Klobes ◽  
Andreas F. Thünemann ◽  
Klaus Rademann ◽  
Franziska Emmerling

2021 ◽  
Author(s):  
Isabelle Simonsson ◽  
Philip Gärdhagen ◽  
Moira Andrén ◽  
Pui Lam Tam ◽  
Zareen Abbas

(Fe)-MOF-235 and (Fe)-MIL-101 are two well-studied iron(III) terephthalate metal-organic frameworks (MOFs) with dissimilar crystal structures and topologies. Previously reported syntheses of the former show greatly varying surface areas, indicating a...


Author(s):  
Jiajun Song ◽  
Jianzhong Zheng ◽  
Anneng Yang ◽  
Hong Liu ◽  
Zeyu Zhao ◽  
...  

Two-dimensional (2D) conductive metal-organic frameworks (MOFs) can not only inherit the high porosity and tailorability of traditional MOFs but also exhibit unique charge transport properties, offering promising opportunities for applications...


2021 ◽  
Vol 303 ◽  
pp. 122547
Author(s):  
Tong Gao ◽  
Hui-Juan Tang ◽  
Shu-Yi Zhang ◽  
Jian-Wei Cao ◽  
Yi-Nong Wu ◽  
...  

2016 ◽  
Vol 12 (1) ◽  
pp. 14
Author(s):  
Prapti Rahayu ◽  
Witri Wahyu Lestari

<p>Metal-organic frameworks (MOFs) are porous coordination polymer containing bi-or polidentate organic linker coordinated with inorganic part, such as metal oxide cluster or metal cation as node which called as secondary building unit (SBU) to form infinite structure. Due to high porosity and surface area, good thermal stability as well as the availability of unsaturated metal center or the linker influence attracts the interaction with gases, thus MOFs have potential to be applied as hydrogen storage material. One type of MOFs that have been widely studied is [Zn<sub>4</sub>O(benzene-1,4-dicarboxylate)<sub>3</sub>], namely, MOF-5.Various synthesis method have been developed to obtain optimum results. Characterization of MOF-5 from various synthesis method such as crystallinity, capacity, stability, and quantum dot behavior of MOF-5 have been summarized in this review.</p>


MRS Bulletin ◽  
2009 ◽  
Vol 34 (9) ◽  
pp. 682-690 ◽  
Author(s):  
Omar M. Yaghi ◽  
Qiaowei Li

AbstractReticular chemistry concerns the linking of molecular building blocks into predetermined structures using strong bonds. We have been working on creating and developing the conceptual and practical basis of this new area of research. As a result, new classes of crystalline porous materials have been designed and synthesized: metal-organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks. Crystals of this type have exceptional surface areas (2,000−6,000 m2/g) and take up voluminous amounts of hydrogen (7.5 wt% at 77 K and 3−4 × 106 Pa), methane (50 wt% at 298 K and 2.5 × 106 Pa), and carbon dioxide (140 wt% at 298 K and 3 × 106 Pa). We have driven the basic science all the way to applications without losing sight of our quest for understanding the underlying molecular aspects of this chemistry. The presentation was focused on the design concepts, synthesis, and structure of these materials, with emphasis on their applications to onboard energy storage.


2009 ◽  
Vol 122 (4) ◽  
pp. 724-727 ◽  
Author(s):  
Tomislav Friščić ◽  
David G. Reid ◽  
Ivan Halasz ◽  
Robin S. Stein ◽  
Robert E. Dinnebier ◽  
...  

2009 ◽  
Vol 49 (4) ◽  
pp. 712-715 ◽  
Author(s):  
Tomislav Friščić ◽  
David G. Reid ◽  
Ivan Halasz ◽  
Robin S. Stein ◽  
Robert E. Dinnebier ◽  
...  

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