Electrolyte-gated transistors based on phenyl-C61-butyric acid methyl ester (PCBM) films: bridging redox properties, charge carrier transport and device performance

2018 ◽  
Vol 54 (43) ◽  
pp. 5490-5493 ◽  
Author(s):  
Tian Lan ◽  
Francesca Soavi ◽  
Massimo Marcaccio ◽  
Pierre-Louis Brunner ◽  
Jonathan Sayago ◽  
...  
Keyword(s):  
Electronic Transport ◽  
Carrier Transport ◽  
Acid Methyl Ester ◽  
Redox Properties ◽  
Device Performance ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester ◽  
Electron Transfer Properties ◽  
Transfer Properties ◽  
Shed Light

We shed light on the correlation between electron transfer properties, ionic and electronic transport as well as device performance in ionic liquid (IL)-gated PCBM transistors.

Optical Absorption Enhancement in Polymer BHJ thin Film Using Ag Nanostructures: A Simulation Study

2020 ◽  
Vol 16 (4) ◽  
pp. 556-567
Author(s):  
Asma Khalil ◽  
Zubair Ahmad ◽  
Farid Touati ◽  
Mohamed Masmoudi
Keyword(s):  
Absorption Spectrum ◽  
Solar Cell ◽  
Methyl Ester ◽  
Butyric Acid ◽  
Organic Solar Cell ◽  
Short Circuit ◽  
Acid Methyl Ester ◽  
Short Circuit Current ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester

Background: The photo-absorption and light trapping through the different layers of the organic solar cell structures are a growing concern now-a-days as it affects dramatically the overall efficiency of the cells. In fact, selecting the right material combination is a key factor in increasing the efficiency in the layers. In addition to good absorption properties, insertion of nanostructures has been proved in recent researches to affect significantly the light trapping inside the organic solar cell. All these factors are determined to expand the absorption spectrum and tailor it to a wider spectrum. Objective: The purpose of this investigation is to explore the consequence of the incorporation of the Ag nanostructures, with different sizes and structures, on the photo absorption of the organic BHJ thin films. Methods: Through a three-dimensional Maxwell solver software, Lumerical FDTD, a simulation and comparison of the optical absorption of the three famous organic materials blends poly(3- hexylthiophene): phenyl C71 butyric acid methyl ester (P3HT:PCBM), poly[N-9″-heptadecanyl-2,7- carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)]: phenyl C71 butyric acid methyl ester (PCDTBT:PCBM) and poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene)-alt- 4,7-(2,1,3-benzothiadiazole)]: phenyl C71 butyric acid methyl ester (PCDPDTBT:PCBM) has been conducted. Furthermore, FDTD simulation study of the incorporation of nanoparticles structures with different sizes, in different locations and concentrations through a bulk heterojunction organic solar cell structure has also been performed. Results: It has been demonstrated that embedding nanostructures in different locations of the cell, specifically in the active layer and the hole transporting layer had a considerable effect of widening the absorption spectrum and increasing the short circuit current. The effect of incorporation the nanostructures in the active layer has been proved to be greater than in the HTL. Furthermore, the comparison results showed that, PCDTBT:PCBM is no more advantageous over P3HT:PCBM and PCPDTBT:PCBM, and P3HT:PCBM took the lead and showed better performance in terms of absorption spectrum and short circuit current value. Conclusion: This work revealed the significant effect of size, location and concentration of the Ag nanostructures while incorporated in the organic solar cell. In fact, embedding nanostructures in the solar cell widen the absorption spectrum and increases the short circuit current, this result has been proven to be significant only when the nanostructures are inserted in the active layer following specific dimensions and structures.

scholarly journals A comparative approach to enhance the electrical performance of PEDOT:PSS as transparent electrode for organic solar cells

2019 ◽  
Vol 28 (1) ◽  
pp. 66-73
Author(s):  
Ismail Borazan ◽  
Ayşe Celik Bedeloğlu ◽  
Ali Demir
Keyword(s):  
Solar Cells ◽  
Organic Solar Cells ◽  
Isopropyl Alcohol ◽  
Power Conversion ◽  
Acid Methyl Ester ◽  
Transparent Electrode ◽  
Electrical Performance ◽  
Comparative Approach ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester

In this article, the improvement in electrical performance of poly(3,4-ethylenedioxythiophene)–poly(styrenesulfonate) (PEDOT:PSS) as the transparent electrode doped with different additives (ethylene glycol (EG), isopropyl alcohol) or treatment of sulfuric acid was enhanced that organic solar cells (OSCs) were produced by using poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl C61 butyric acid methyl ester. OSCs were fabricated by the doped or treated PEDOT:PSS films as transparent electrodes. The photoelectrical measurements were carried out and the effects of doping or treatment were compared. As a result, EG-added PEDOT:PSS electrode showed the best power conversion efficiency value of 1.87% among the PEDOT:PSS anodes.

Sterically controlled azomethine ylide cycloaddition polymerization of phenyl-C61-butyric acid methyl ester

2016 ◽  
Vol 52 (36) ◽  
pp. 6107-6110 ◽  
Author(s):  
Meera Stephen ◽  
Hasina H. Ramanitra ◽  
Hugo Santos Silva ◽  
Simon Dowland ◽  
Didier Bégué ◽  
...  
Keyword(s):  
Thin Films ◽  
Methyl Ester ◽  
Butyric Acid ◽  
Acid Methyl Ester ◽  
Azomethine Ylide ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester ◽  
Solution Processable

PCBM is polymerised using the SACAP route to give solution processable thin films and raised LUMOs.

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