A high-nuclearity isopolyoxotungstate based manganese cluster: one-pot synthesis and step-by-step assembly
A high-nuclearity manganese–tungsten supercluster Na8H32[{MnIV24MnIII12O28(H2O)23}2(W24O120)2]·66H2O (Mn72W48) has been successfully synthesized and its formation mechanism is investigated by ESI-MS.