scholarly journals Giant exchange coupling and field-induced slow relaxation of magnetization in Gd2@C79N with a single-electron Gd–Gd bond

2018 ◽  
Vol 54 (23) ◽  
pp. 2902-2905 ◽  
Author(s):  
G. Velkos ◽  
D. S. Krylov ◽  
K. Kirkpatrick ◽  
X. Liu ◽  
L. Spree ◽  
...  

Single-electron Gd–Gd bond in Gd2@C79N results in giant ferromagnetic coupling between local 4f magnetic moments and unpaired electron spin.

Author(s):  
M. M. Glazov

The discussion of the electron spin decoherence and relaxation phenomena via the hyperfine interaction with host lattice spins is presented here. The spin relaxation processes processes limit the conservation time of spin states as well as the response time of the spin system to external perturbations. The central spin model, where the spin of charge carrier interacts with the bath of nuclear spins, is formulated. We also present different methods to calculate the spin dynamics within this model. Simple but physically transparent semiclassical treatment where the nuclear spins are considered as largely static classical magnetic moments is followed by more advanced quantum mechanical approach where the feedback of electron spin dynamics on the nuclei is taken into account. The chapter concludes with an overview of experimental data and its comparison with model calculations.


Author(s):  
Chuyang Liu ◽  
Tao Jiang ◽  
Tian Gao ◽  
Guangxian Xia ◽  
Yufan Cao ◽  
...  

It is well known that both hard/soft magnetic exchange-coupling and ferroelectric-ferromagnetic coupling could facilitate the microwave absorption behavior. Herein, we propose the BaZrxFe12-xO19/Fe3O4/BaZrO3 composites to integrate the advantages of the...


2017 ◽  
Vol 31 (31) ◽  
pp. 1750247
Author(s):  
Qingyu Huo ◽  
Zhenchao Xu ◽  
Linfeng Qu

Both blue and red shifts in the absorption spectrum of Co-doped ZnO have been reported at a similar concentration range of doped Co. Moreover, the sources of magnetism of Co-doped ZnO are controversial. To solve these problems, the geometry optimization and energy of different Co-doped ZnO systems were calculated at the states of electron spin polarization and nonspin polarization by adopting plane-wave ultra-soft pseudopotential technology based on density function theory. At the state of electron nonspin polarization, the total energies increased as the concentration of Co-doped increased. The doped systems also became unstable. The formation energies increased and doping became difficult. Furthermore, the band gaps widened and the absorption spectrum exhibited a blue shift. The band gaps were corrected by local-density approximation + [Formula: see text] at the state of electron spin polarization. The magnetic moments of the doped systems weakened as the concentration of doped Co increased. The magnetic moments were derived from the coupling effects of [Formula: see text]–[Formula: see text]. The band gaps narrowed and the absorption spectrum exhibited a red shift. The inconsistencies of the band gaps and absorption spectrum at the states of electron spin polarization and nonspin polarization were first discovered in this research, and the sources of Co-doped ZnO magnetism were also reinterpreted.


2007 ◽  
Vol 46 (10A) ◽  
pp. 6579-6585 ◽  
Author(s):  
Pham Nam Hai ◽  
Satoshi Sugahara ◽  
Masaaki Tanaka

2001 ◽  
Vol 70 (7) ◽  
pp. 535-541 ◽  
Author(s):  
Anatolii L Buchachenko ◽  
Fedor I Dalidchik ◽  
Sergei A Kovalevskii ◽  
Boris R Shub

2017 ◽  
Vol 19 (12) ◽  
pp. 123006 ◽  
Author(s):  
S Bednarek ◽  
J Pawłowski ◽  
M Górski ◽  
G Skowron

2017 ◽  
Vol 19 (1) ◽  
pp. 49-53 ◽  
Author(s):  
V. I. Borovkov

Magnetic field sensitive fluorescence from irradiated propylene carbonate solutions indicates the existence of previously unobserved radical cations formed from the solvent molecules.


2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Tomohiro Otsuka ◽  
Takashi Nakajima ◽  
Matthieu R. Delbecq ◽  
Shinichi Amaha ◽  
Jun Yoneda ◽  
...  

ChemPlusChem ◽  
2020 ◽  
Vol 85 (9) ◽  
pp. 2093-2104
Author(s):  
Fumito Tani ◽  
Masahiro Narita ◽  
Toshihiro Murafuji

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