Stereoselective synthesis of a Podophyllum lignan core by intramolecular reductive nickel-catalysis

2018 ◽  
Vol 54 (16) ◽  
pp. 2040-2043 ◽  
Author(s):  
Jian Xiao ◽  
Xiao-Wei Cong ◽  
Gui-Zhen Yang ◽  
Ya-Wen Wang ◽  
Yu Peng
Keyword(s):  
Stereoselective Synthesis ◽  
Nickel Catalysis

Ni-catalyzed intramolecular coupling for a stereodivergent construction of a THN[2,3-c]furan core embedded in bioactive Podophyllum lignans, is developed.

scholarly journals Ligand-redox assisted nickel catalysis toward stereoselective synthesis of (n+1)-membered cycloalkanes from 1,n-diols with methyl ketones

2021 ◽  
Author(s):  
Amreen K Bains ◽  
Abhishek Kundu ◽  
Debashis Adhikari ◽  
Debabrata Maiti
Keyword(s):  
Nickel Catalyst ◽  
Methyl Ketone ◽  
Stereoselective Synthesis ◽  
Nickel Catalysis ◽  
Methyl Ketones

A well-defined, bench-stable nickel catalyst is presented here, that can conduct double alkylation of a methyl ketone to realize a wide variety of cycloalkanes. The performance of the catalyst hinges...

Highly stereoselective synthesis of aryl/heteroaryl-C-nucleosides via the merger of photoredox and nickel catalysis

2019 ◽  
Vol 55 (97) ◽  
pp. 14657-14660 ◽  
Author(s):  
Yingying Ma ◽  
Shihui Liu ◽  
Yifan Xi ◽  
Hongrui Li ◽  
Kai Yang ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Nickel Catalysis ◽  
Cross Coupling Reaction

A photoredox/nickel dual-catalyzed decarboxylative cross-coupling reaction of anomeric ribosyl/deoxyribosyl acids with aryl/heteroaryl bromides has been developed.

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