Highly sensitive electrochemical sensing of para-chloronitrobenzene using a carbon nanohorn–nanotube hybrid modified electrode

2019 ◽  
Vol 11 (8) ◽  
pp. 1125-1130 ◽  
Author(s):  
Gangbing Zhu ◽  
Mwenze Nkulu Fiston ◽  
Junjuan Qian ◽  
Odoom Jibrael Kingsford

A novel three-dimensional nanohybrid composed of carbon nanohorns and carbon nanotubes was prepared via a simple ultrasonication process for electrochemical sensing of para-chloronitrobenzene.

A modified glassy carbon electrode (GCE) compositing multi-walled carbon nanotubes (MWCNTs), Nafion and bismuth film was prepared and applied for the sensitive detection of trace Pb (II). MWCNTs were dispersed into ethanol by ultrasonication in the presence of Nafion and the nanotubes are coated onto the bare GCE. After that, an extra Nafion adhesion agent is added to the electrode. By the in situ plating, a bismuth film was fabricated on the MWCNTs-NA/GCE, making the desired electrode, MWCNTs-NA-Bi/GCE. The modified electrode was characterized by differential pulse anodic stripping voltammetry, scanning electron microscopy, and cyclic voltammetry. A deposition potential of –1.4 V (vs. Ag/AgCl) and a deposition time of 300 s were applied to the working electrode under stirred conditions after optimizing. Nanotubes and Nafion concentrations and pH were carefully optimized to determine trace lead ions by using the electrode as an electrochemical-sensing platform. Nafion effectively increased the stability and adhesivity of the composite film. The MWCNTs-NA-Bi film modified electrode can remarkably increase the anodic peak current of Pb2+. The sensitivity of MWCNTs-NA-Bi/GCE is 4.35 times higher than that of the bare GCE with bismuth film. The prepared electrode showed excellent stability and reproducibility and can be applied for determination of Pb2+ contained wastewater.


2022 ◽  
Author(s):  
Qiaoling Wu ◽  
Chun Ji ◽  
Lingli Zhang ◽  
Qingli Shi ◽  
Yuangen Wu ◽  
...  

The work presented here describes a highly sensitive and simple electrochemical sensor for the detection of Sudan I dye based on MoS2 heterogeneous nanosheets (1T@2H-MoS2) and carboxylated carbon nanotubes (cMWCNTs)...


2019 ◽  
Vol 30 (8) ◽  
pp. 1216-1224 ◽  
Author(s):  
Mohammad Charara ◽  
Mohammad Abshirini ◽  
Mrinal C Saha ◽  
M Cengiz Altan ◽  
Yingtao Liu

This article presents three-dimensional printed and highly sensitive polydimethylsiloxane/multi-walled carbon nanotube sensors for compressive strain and pressure measurements. An electrically conductive polydimethylsiloxane/multi-walled carbon nanotube nanocomposite is developed to three-dimensional print compression sensors in a freestanding and layer-by-layer manner. The dispersion of multi-walled carbon nanotubes in polydimethylsiloxane allows the uncured nanocomposite to stand freely without any support throughout the printing process. The cross section of the compression sensors is examined under scanning electron microscope to identify the microstructure of nanocomposites, revealing good dispersion of multi-walled carbon nanotubes within the polydimethylsiloxane matrix. The sensor’s sensitivity was characterized under cyclic compression loading at various max strains, showing an especially high sensitivity at lower strains. The sensing capability of the three-dimensional printed nanocomposites shows minimum variation at various applied strain rates, indicating its versatile potential in a wide range of applications. Cyclic tests under compressive loading for over 8 h demonstrate that the long-term sensing performance is consistent. Finally, in situ micromechanical compressive tests under scanning electron microscope validated the sensor’s piezoresistive mechanism, showing the rearrangement, reorientation, and bending of the multi-walled carbon nanotubes under compressive loads, were the main reasons that lead to the piezoresistive sensing capabilities in the three-dimensional printed nanocomposites.


2020 ◽  
Vol 44 (37) ◽  
pp. 15975-15982
Author(s):  
Xueliang Niu ◽  
Weili Zhang ◽  
Yan Huang ◽  
Likai Wang ◽  
Zhongfang Li ◽  
...  

A novel electrochemical method for highly sensitive determination of baicalein was developed with Au@Ag/3DNGA as signal amplifier.


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